Doublet and quartet states of Li2-

被引:6
|
作者
Hogreve, H
机构
[1] CNRS, Ctr Phys Theor, F-13288 Marseille 9, France
[2] IFISR, D-31174 Schellerten, Germany
来源
EUROPEAN PHYSICAL JOURNAL D | 2000年 / 8卷 / 01期
关键词
D O I
10.1007/s100530050011
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Electronic states of the molecular lithium anion are investigated by configuration-interaction calculations. Comparison with the analogously computed potential energy curves for the lowest singlet and triplet states of the neutral Li-2 shows that in addition to the well-known stable ground state X(2)Sigma(u)(+) there also exist metastable excited states of Li-2(-). Within the quartet sector, two candidates for such long-lived states are identified and their spectroscopic properties studied.
引用
收藏
页码:85 / 91
页数:7
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