A Clear- Cut Example of Selective Bpin - Bdan Activation and Precise Bdan Transfer on Boron Conjugate Addition

被引：58

作者：

Cid, Jessica ^{[1
]}

Carbo, Jorge J. ^{[1
]}

Fernandez, Elena ^{[1
]}

机构：

[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona, Spain

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 13期

关键词：

boration; density functional theory; diboron reagents; nucleophilic boron; BORYLALKENES ASYMMETRIC-SYNTHESIS; CROSS-COUPLING MODULES; BETA-BORATION; DIBORON REAGENTS; CATALYST DESIGN; DERIVATIVES; BORYLATION; ACIDS; HYDROBORATION; OLIGOARENES;

D O I：

10.1002/chem.201304615

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Activating the non-symmetrical BpinBdan diboron reagent with alkoxide leads to the formation of two possible adducts: MeO(-)BpinBdan or MeO(-)BdanBpin. Experimental and theoretical investigation confirms that the MeO(-)Bpin interaction is preferred and thus selective formation of a CBdan bond upon reaction with an activated CC bond.

引用

页码：3616 / 3620

页数：5

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