Polymer-derived SiAlCN ceramics resist oxidation at 1400 °C

被引:121
作者
Wang, Yiguang
Fan, Yi
Zhang, Ligong
Zhang, Wenge
An, Linan
机构
[1] Univ Cent Florida, Adv Mat Proc & Anal Ctr, Orlando, FL 32816 USA
[2] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Lab Excited State Proc, Changchun 130032, Peoples R China
[3] Sporian Microsyst Technol Inc, Boulder, CO 80026 USA
关键词
SiAlCN; oxidation; precursor;
D O I
10.1016/j.scriptamat.2006.05.004
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The oxidation kinetics of polymer-derived SiAlCN ceramics are determined at 1400 degrees C by measuring oxide-scale thickness as a function of oxidation time. The results reveal that the SiAlCN ceramics possess much better oxidation resistance than polymer-derived SiCN without Al, pure SiC and Si3N4. X-ray diffraction studies reveal that the oxide scales consist of cristobalite, plus a small amount of mullite for the sample with high aluminum-content. The reason that the SiAlCNs exhibited better oxidation resistance is discussed. (c) 2006 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:295 / 297
页数:3
相关论文
共 25 条
[1]  
An LA, 1998, J AM CERAM SOC, V81, P1349
[2]   Carbon-nanotube-reinforeed polymer-derived ceramic composites [J].
An, LN ;
Xu, WX ;
Rajagopalan, S ;
Wang, CM ;
Wang, H ;
Fan, Y ;
Zhang, LG ;
Jiang, DP ;
Kapat, J ;
Chow, L ;
Guo, BH ;
Liang, J ;
Vaidyanathan, R .
ADVANCED MATERIALS, 2004, 16 (22) :2036-+
[3]   Silicoaluminum carbonitride with anomalously high resistance to oxidation and hot corrosion [J].
An, LN ;
Wang, YG ;
Bharadwaj, L ;
Zhang, LG ;
Fan, Y ;
Jiang, DP ;
Sohn, YH ;
Desai, VH ;
Kapat, J ;
Chow, LC .
ADVANCED ENGINEERING MATERIALS, 2004, 6 (05) :337-340
[4]   Reactions and diffusion of water and oxygen molecules in amorphous SiO2 -: art. no. 055508 [J].
Bakos, T ;
Rashkeev, SN ;
Pantelides, ST .
PHYSICAL REVIEW LETTERS, 2002, 88 (05) :4
[5]  
Baldus HP, 1997, ANGEW CHEM INT EDIT, V36, P329
[6]   Oxidation behavior of a fully dense polymer-derived amorphous silicon carbonitride ceramic [J].
Bharadwaj, L ;
Fan, Y ;
Zhang, LG ;
Jiang, DP ;
An, LN .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2004, 87 (03) :483-486
[7]  
Butchereit E, 2001, J AM CERAM SOC, V84, P2184, DOI 10.1111/j.1151-2916.2001.tb00985.x
[8]   High-temperature mechanical properties of Si-B-C-N-precursor-derived amorphous ceramics and the applicability of deformation models developed for metallic glasses [J].
Christ, M ;
Thurn, G ;
Weinmann, M ;
Bill, J ;
Aldinger, F .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2000, 83 (12) :3025-3032
[9]   GENERAL RELATIONSHIP FOR THERMAL OXIDATION OF SILICON [J].
DEAL, BE ;
GROVE, AS .
JOURNAL OF APPLIED PHYSICS, 1965, 36 (12) :3770-&
[10]   Polymer-ceramic conversion of liquid polyaluminasilazanes for SiAlCN ceramics [J].
Dhamne, A ;
Xu, WX ;
Fookes, BG ;
Fan, Y ;
Zhang, LG ;
Burton, S ;
Hu, JZ ;
Ford, J ;
An, LA .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (09) :2415-2419