Supramolecular chirality in coordination chemistry

被引：119

作者：

Seeber, Georg ^{[1
]}

Tiedemann, Bryan E. F. ^{[1
]}

Raymond, Kenneth N. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

SUPRAMOLECULAR CHIRALITY | 2006年 / 265卷

关键词：

chirality; coordination compounds; guest inclusion; host-guest interactions; supramolecular chemistry;

D O I：

10.1007/128_033

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Supramolecular chirality is generated from assemblies based on supramolecular interactions such as hydrogen bonding, van der Waals and metal-ligand coordinative interactions. In this chapter, we discuss chiral supramolecular architectures that are based on metal-ligand coordination. Emphasis is given to ensembles that are formed exclusively from achiral building units and thus rely on metal coordination geometries or asymmetric ligand arrangements in order to generate chirality via supramolecular (coordinative) interactions. Particular interest is given to assemblies that exhibit chiral cavities with potential for guest encapsulation for recognition, storage, and utilization as nano-reaction vessels. Examples of chiral architectures are presented that resemble molecular symmetries of helicates, trigonal (anti)prisms, tetrahedra, trigonal bipyramids, octahedra and cuboctahedra.

引用

页码：147 / 183

页数：37

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