Alburnite, Ag8GeTe2S4, a new mineral species from the Rosia Montana Au-Ag epithermal deposit, Apuseni Mountains, Romania

被引:10
作者
Tamas, Calin G. [1 ,2 ]
Grobety, Bernard [2 ]
Bailly, Laurent [3 ]
Bernhardt, Heinz-Juergen [4 ]
Minut, Adrian [5 ]
机构
[1] Univ Babes Bolyai, Dept Geol, Cluj Napoca 400084, Romania
[2] Univ Fribourg, Dept Geosci, CH-1700 Fribourg, Switzerland
[3] Bur Rech Geol & Minieres, F-45060 Orleans, France
[4] Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44801 Bochum, Germany
[5] Rosia Montana Gold Corp, Rosia Montana, Alba County, Romania
关键词
Alburnite; new mineral; germanium-tellurium sulfosalts; Rosia Montana; Apuseni Mountains; Romania; CRYSTAL; CANFIELDITE; CAPILLITAS; ARGENTINA; CATAMARCA; NEOGENE; SILVER;
D O I
10.2138/am.2014.4557
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
Alburnite, ideally Ag8GeTe2S4, was discovered in the Carnicel vein from the Rosia Montana epithermal Au-Ag ore deposit, Apuseni Mountains, Romania. The new mineral is associated with tetrahedrite, galena, pyrite, sphalerite, chalcopyrite, and tellurides (hessite, altaite, and sylvanite). Associated gangue minerals are rhodochrosite, quartz, calcite, and rhodonite. Alburnite was observed only at the microscopic scale as rounded to sub-rounded grains, veinlets or irregular inclusions hosted mainly by tetrahedrite, hessite, and rhodochrosite. Due to the small size of alburnite grains observed so far it was not possible to determine some macroscopic properties; reported properties are based on microscopic observations. The mineral has a metallic luster and is opaque. It is non-fluorescent and has an estimated Mohs hardness of 4. The mineral shows no cleavage. Density could not be measured because of the small grain size, but calculated density based on the empirical formula is 7.828 g/cm(3). In plane-polarized light in air, alburnite is gray-blue with a bluish tint. It shows no pleochroism or bireflectance in air. Between crossed polars alburnite is isotropic and internal reflections have not been observed in air. The mineral decomposes in intense light. Reflectance minimum values in air (in percents) are: 470 nm 29.70; 546 nm 28.00; 589 nm 27.35; 650 nm 26.95. The average chemical composition based on 18 electron microprobe analyses from 9 different grains in one polished section is (in wt%): Ag 65.49, Ge 4.82, Te 20.16, S 9.66, total 100.13. The ideal formula of alburnite, Ag8GeTe2S4, based on 15 apfu requires Ag 65.43, Ge 5.50, Te 19.35, S 9.72, total 100.00 wt%. Features of the crystal structure of alburnite were determined based on electron backscattered diffraction and transmission electron microscopy. Alburnite is cubic, space group F43m, with unit-cell parameters a = 10.4(1) angstrom, V = 1125(30) angstrom(3), Z = 4. The strongest eight calculated XRD lines [d in angstrom(I)(hkl)] are: 6.004(67)(111), 3.136(48)(113), 3.002(100)(222), 2.600(26)(004), 2.123(33)(224), 2.002(61)(115), 1.838(76)(044), and 1.644(12)(026). The name of the new mineral alburnite is derived from the Latin name of the locality. Rosia Montana Au-Ag deposit was known during the Roman period as Alburnus Major. The mineral and the mineral name have been approved by the Commission on New Minerals, Nomenclature and Classification, IMA 2012-073.
引用
收藏
页码:57 / 64
页数:8
相关论文
共 41 条
  • [1] Andronescu A., 1962, REV MINELOR, VXIII, P498
  • [2] [Anonymous], STUDI SI CERCETARI G
  • [3] [Anonymous], 1999, STUD U BABES BOLYAIG
  • [4] [Anonymous], 2006, Society of Economic Geologists Newsletter
  • [5] [Anonymous], CAN MINERAL
  • [6] [Anonymous], 1941, Anuarul Institutului Geologic Roman
  • [7] [Anonymous], 2009, ArcheoSciences Rev. d'archaeometrie
  • [8] Te-rich argyrodite occurrence in Rosia Montana ore deposit, Apuseni Mountains, Romania
    Bailly, L
    Tamas, CG
    Minut, A
    [J]. COMPTES RENDUS GEOSCIENCE, 2005, 337 (08) : 755 - 762
  • [9] Lead isotope analyses of gold-silver ores from Roia Montana (Romania): a first step of a metal provenance study of Roman mining activity in Alburnus Maior (Roman Dacia)
    Baron, S.
    Tamas, C. G.
    Cauuet, B.
    Munoz, M.
    [J]. JOURNAL OF ARCHAEOLOGICAL SCIENCE, 2011, 38 (05) : 1090 - 1100
  • [10] Benea M., 2010, ACTA MINERALOGICA PE, V21