A theoretical investigation has been made on the head-on collision of cylindrical and spherical electron-acoustic solitary waves in a non-Maxwellian plasma composed of stationary ions, cold fluid electrons, and superthermal electrons obeying kappa velocity distribution. By using the extended Poincar,-Lighthill-Kuo perturbation method, the effects of plasma parameters, especially the superthermal effect on the interaction of colliding solitary waves are studied. It is found that there are both positive and negative colliding phase shifts for each colliding wave in its traveling direction. Also, it is shown that the solitary waves received the largest colliding phase shifts in spherical geometry, followed by the cylindrical and planar geometries.