A Ring-Opening Metathesis Polymerization Route to Alkaline Anion Exchange Membranes: Development of Hydroxide-Conducting Thin Films from an Ammonium-Functionalized Monomer

被引：219
作者：
Clark, Timothy J. [1 ]
Robertson, Nicholas J. [1 ]
Kostalik, Henry A. [1 ]
Lobkovsky, Emil B. [1 ]
Mutolo, Paul F. [1 ]
Abruna, Hector D. [1 ]
Coates, Geoffrey W. [1 ]
机构：
[1] Cornell Univ, Dept Chem & Chem Biol, Baker Lab, Ithaca, NY 14853 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 36期
基金：
加拿大自然科学与工程研究理事会;
关键词：
FUEL-CELLS; TEMPERATURE; POLYMERS;
D O I：
10.1021/ja905242r
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the development of a facile ring-opening olefin metathesis route to alkaline anion exchange membranes via the copolymerization of a tetraalkylammonium-functionalized norbornene with dicyclopentadiene. The thin films generated are mechanically strong and exhibit high hydroxide conductivities and exceptional methanol tolerance.
引用
收藏
页码：12888 / +
页数：3
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