EPR studies of Cu2+-doped bis(saccharinato)bis(pyridine)zinc(II) single crystals

被引：16

作者：

Bozkurt, E

Kartal, I ^{[1
]}

Karabulut, B

Yesilel, OZ

机构：

[1] Ondokuz Mayis Univ, Fac Sci, Dept Phys, Samsun, Turkey

[2] Ondokuz Mayis Univ, Fac Sci, Dept Chem, Samsun, Turkey

来源：

APPLIED MAGNETIC RESONANCE | 2004年 / 26卷 / 03期

关键词：

D O I：

10.1007/BF03166801

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The electron paramagnetic resonance spectra of Cu2+ impurities in bis(saccharinato)bis(pyridine)zinc(H) single crystals have been studied at room temperature in three mutually perpendicular planes. The angular variation of the spectra indicates the substitution of the host Zn2+ with Cu2+. Two magnetically inequivalent sites for Cu2+ have been observed. The spectra were fitted to the rhombic spin Hamiltonian. The spin Hamiltonian parameters and the molecular orbital coefficients were evaluated for the two sites. The ground-state wave function of Cu2+ ion in the lattice has been constructed.

引用

页码：275 / 282

页数：8

共 19 条

[1] EPR measurements in copper saccharinate single crystals [J].