Surface Modification of Mild Steel by Orthophenylenediamine and Its Corrosion Study

被引:0
作者
Sachin, H. P. [1 ]
Khan, M. H. Moinuddin [1 ]
Bhujangaiah, N. S. [1 ]
机构
[1] Jawaharlal Nehru Natl Coll Engn, Dept Chem, Shimoga 577204, Karnataka, India
关键词
Surface modification; Corrosion inhibition; Mild steel; COLD-ROLLED STEEL; ACID CORROSION; INHIBITION; HCL; TEMPERATURE; DISSOLUTION; ADSORPTION;
D O I
暂无
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
An attempt has been made towards the synthesis of strongly adherent orthophenylenediamine (OPD) coating on mild steel substrates, with an objective of using the OPD for corrosion protection of steel in hydrochloric acid medium. In this work, the OPD coatings were obtained by electrochemical reduction of orthonitroaniline (ONA) using dilute sulphuric acid as supporting electrolyte. The characterization of the coating was done by infrared spectroscopic and scanning electron microscopic studies. The non porous nature of the coating was determined by ferroxyl test. The performance of OPD as protective coating against corrosion of mild steel in aqueous hydrochloric acid was assessed by open circuit potential, potentiodynamic polarization, weight loss method. These studies revealed that the OPD coating on mild steel provide very good protection to mild steel against corrosion in hydrochloric acid environment.
引用
收藏
页码:134 / 143
页数:10
相关论文
共 30 条
[1]   The inhibition of 4-(2′-amino-5′-methylphenylazo) antipyrine on corrosion of mild steel in HCl solution [J].
Abd El Rehim, SS ;
Ibrahim, MAM ;
Khalid, KF .
MATERIALS CHEMISTRY AND PHYSICS, 2001, 70 (03) :268-273
[2]  
Abd EL-REHIM S.S., 2001, J APP ELECTROCHEM, V31, P429
[3]   Application of the kinetic-thermodynamic model for inhibition of acid corrosion of steel by inhibitors containing sulfur and nitrogen [J].
AbdElNabey, BA ;
Khamis, E ;
Ramadan, MS ;
ElGindy, A .
CORROSION, 1996, 52 (09) :671-679
[4]   Effect of temperature on stability of adsorbed inhibitors on steel in phosphoric acid solution [J].
Ameer, MA ;
Khamis, E ;
Al-Senani, G .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2002, 32 (02) :149-156
[5]   INHIBITION OF ACID CORROSION OF STEEL BY SOME S-ALKYLISOTHIOURONIUM IODIDES [J].
ARAB, ST ;
NOOR, EA .
CORROSION, 1993, 49 (02) :122-129
[6]   Corrosion and hydrogen permeation inhibition for mild steel in HCl by isomers of organic compounds [J].
Babu, BR ;
Holze, R .
BRITISH CORROSION JOURNAL, 2000, 35 (03) :204-209
[7]   1,10,-PHENANTHROLINE AS CORROSION-INHIBITOR FOR MILD-STEEL IN SULFURIC-ACID SOLUTION [J].
BANERJEE, SN ;
MISRA, S .
CORROSION, 1989, 45 (09) :780-783
[8]   Inhibitor effects of triazole derivatives on corrosion of mild steel in acidic media [J].
Bentiss, F ;
Traisnel, M ;
Lagrenee, M .
BRITISH CORROSION JOURNAL, 2000, 35 (04) :315-320
[9]   Inhibition of acidic corrosion of mild steel by 3,5-diphenyl-4H-1,2,4-triazole [J].
Bentiss, F ;
Traisnel, M ;
Gengembre, L ;
Lagrenée, M .
APPLIED SURFACE SCIENCE, 2000, 161 (1-2) :194-202
[10]   An investigation of some Schiff bases as corrosion inhibitors for austenitic chromium-nickel steel in H2SO4 [J].
Bilgiç, S ;
Çaliskan, N .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (01) :79-83