Preliminary Structural Analysis of High Molecular Weight Alkaline Degradation Products of Sucrose

被引:2
作者
Zhu, Zhongyan [1 ]
Li, Kai [1 ]
Li, Wen [2 ,3 ]
机构
[1] Guangxi Univ, Coll Light Ind & Food Engn, Nanning 530004, Peoples R China
[2] Guangxi Univ Nationalities, Coll Chem & Chem Engn, Nanning 530008, Peoples R China
[3] Guangxi Univ, Collaborat Innovat Ctr Guangxi Sugarcane Ind, Nanning 530004, Peoples R China
关键词
Structural analysis; High molecular weight; Alkaline degradation; Sucrose; SUGAR; MELANOIDIN; FRUCTOSE; GLUCOSE; FTIR; NMR;
D O I
10.1007/s12355-020-00902-2
中图分类号
S3 [农学(农艺学)];
学科分类号
0901 ;
摘要
The high molecular weight alkaline degradation products of sucrose (HMWADPS) are the colored substances in sugar juice. Few studies have been conducted to elucidate the structure of HMWADPS. In the present study, the structure of HMWADPS was analyzed by nuclear magnetic resonance and Fourier transform infrared spectroscopy, and the molecular weight of HMWADPS was determined by gel permeation chromatography. The chemical structure of HMWADPS consisted of carbonyl carbon (ketones, aldehyde, and carboxyl), conjugated double bonds, alcoholic hydroxyl, and saturated alkanes. The molecular weight of HMWADPS was calculated to be predominately composed by 19525 and 2357 Da, respectively.
引用
收藏
页码:461 / 465
页数:5
相关论文
共 28 条
  • [21] Permethylation as a strategy for high-molecular-weight polysaccharide structure analysis by nuclear magnetic resonance-Case study of Xylella fastidiosa extracellular polysaccharide
    Ndukwe, Ikenna E.
    Black, Ian
    Castro, Claudia A.
    Vlach, Jiri
    Heiss, Christian
    Roper, Caroline
    Azadi, Parastoo
    MAGNETIC RESONANCE IN CHEMISTRY, 2024, 62 (05) : 370 - 377
  • [22] Tacticity, Isomeric Structural Units and Molecular Weight Determination of Hydroxyl Terminated Polybutadiene by High Field FT-qNMR Spectroscopy
    Mahanta, Abhay Kumar
    ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (12) : 5809 - 5812
  • [23] Hollow-Fiber Ultrafiltration then Centrifugation for LC Analysis of Water-Soluble Sucrose in a Water-Soluble High-Molecular-Mass Gel Matrix
    Junmei Li
    Ye Jiang
    Ting Sun
    Lijuan Kang
    Chromatographia, 2009, 70 : 1023 - 1030
  • [24] Hollow-Fiber Ultrafiltration then Centrifugation for LC Analysis of Water-Soluble Sucrose in a Water-Soluble High-Molecular-Mass Gel Matrix
    Li, Junmei
    Jiang, Ye
    Sun, Ting
    Kang, Lijuan
    CHROMATOGRAPHIA, 2009, 70 (7-8) : 1023 - 1030
  • [25] Structural analysis of biodegradable low-molecular mass copolyesters based on glycolic acid, adipic acid and 1,4 butanediol and correlation with their hydrolytic degradation
    Soulis, Spyridon
    Triantou, Despina
    Weidner, Steffen
    Falkenhagen, Jana
    Simitzis, Johannis
    POLYMER DEGRADATION AND STABILITY, 2012, 97 (11) : 2091 - 2103
  • [26] Structural Analysis and Classification of Low-Molecular-Weight Hyaluronic Acid by Near-Infrared Spectroscopy: A Comparison between Traditional Machine Learning and Deep Learning
    Tian, Weilu
    Zang, Lixuan
    Nie, Lei
    Li, Lian
    Zhong, Liang
    Guo, Xueping
    Huang, Siling
    Zang, Hengchang
    MOLECULES, 2023, 28 (02):
  • [27] Supramolecular interactions in high molecular weight bisdithiocarbamate adducts of divalent Zn(II), Cd(II), and Hg(II): spectral, VBS, and single crystal X-ray structural studies on MS4N2 chromophores
    Ramalingam, K.
    Uma, S.
    Rizzoli, C.
    Marimuthu, G.
    JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (23) : 4123 - 4135
  • [28] Structural analysis of 6-S-(benzoxazol-2-yl)-6-deoxy 1,2:3,4-di-O-isopropylidene-6-thio-alpha-D-galactopyranose by means of X-ray diffraction, high resolution NMR spectroscopy, and molecular modelling
    Lakin, MT
    MouhousRiou, N
    Lorin, C
    Rollin, P
    Kroon, J
    Perez, S
    CARBOHYDRATE RESEARCH, 1996, 290 (02) : 125 - 136