Properties of Cationic Choline-Derived Surfactant with Photolabile Cinnamate Counterion

被引：4
|
作者：
Song, Shili [1 ]
Han, Yabing [1 ]
Hao, Wenli [1 ]
Lu, Jingwen [1 ]
Qian, Yuhua [2 ]
机构：
[1] Henan Normal Univ, Appl Chem, Xinxiang, Peoples R China
[2] Henan Normal Univ, Dept Chem Engn & Technol, Xinxiang, Peoples R China
来源：
TENSIDE SURFACTANTS DETERGENTS | 2017年 / 54卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Choline; cinnamate; viscoelasticity; photoisomerization; VISCOELASTIC WORMLIKE MICELLES; AQUEOUS-SOLUTION; IONIC LIQUIDS; ALKYLPYRIDINIUM SURFACTANTS; PHOTORHEOLOGICAL FLUIDS; VISCOSITY; LIGHT; HYDROPHOBICITY; AGGREGATION; SOLUBILITY;
D O I：
10.3139/113.110479
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A cationic choline-derived surfactant with photolabile cinnamate counterion (tetradecyl-(2-hydroxyethyl)-dimethylammoniumcinnamate, C(14)HDACin) was synthesized. The properties of C(14)HDACin aqueous solutions for pre- or post-UV irradiation were investigated by employing tensiometry, conductance, transmission electron microscopy (TEM) and rheometry. The effect of UV irradiation time on photoisomerization of C(14)HDACin solutions was evaluated, which showed that the photoisomerization efficiency decreases with an increase of C(14)HDACin concentration. After UV irradiation, the fraction of counterion binding (beta) of the C(14)HDACin micelle decreases. However, the value of CMC increases. Rheometry coupled with TEM studies confirmed that the aggregation of C(14)HDACin could transform from wormlike to spherical micelles upon UV irradiation.
引用
收藏
页码：45 / 53
页数：9
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