Anion-π Interactions in Crystal Structures: Commonplace or Extraordinary?

被引：114
|
作者：
Hay, Benjamin P. [1 ]
Custelcean, Radu [1 ]
机构：
[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
来源：
CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 06期
关键词：
HYDROGEN-BOND; AB-INITIO; BINDING; COMPLEXES; BR; RECOGNITION; STRENGTH; DATABASE; RINGS; VAN;
D O I：
10.1021/cg900308b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An in-depth analysis of the distribution of anions about planar six-membered rings in the Cambridge Structural Database reveals anion-pi interactions with charge-neutral pi systems to be extremely rare in crystal structures. The predominant interaction motif is C-H center dot center dot center dot anion hydrogen bonding.
引用
收藏
页码：2539 / 2545
页数：7
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