N-unsubstituted and N-arylated fulleropyrrolidines:: New useful building blocks for C60 functionalization

被引:3
作者
Tong Chen-Hua [1 ]
Wu Zong-Quan [1 ]
Hou Jun-Li [1 ]
Li Zhan-Ting [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
关键词
fullerene; addition reaction; pyrrolidine; functionalization;
D O I
10.1002/cjoc.200690220
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two series of stable and soluble fulleropyrrolidines have been prepared from the reactions of C-60, glycine or its N-arylated derivatives and aliphatic aldehydes or ketones in refluxing toluene or chlorobenzene. The new C-60 derivatives represent new useful building blocks for further preparation of more funcionalized C-60 derivatives.
引用
收藏
页码:1175 / 1179
页数:5
相关论文
共 22 条
[1]   Photoinduced processes in fullerenopyrrolidine and fullerenopyrazoline derivatives substituted with an oligophenylenevinylene moiety [J].
Armaroli, N ;
Accorsi, G ;
Gisselbrecht, JP ;
Gross, M ;
Krasnikov, V ;
Tsamouras, D ;
Hadziioannou, G ;
Gómez-Escalonilla, MJ ;
Langa, F ;
Eckert, JF ;
Nierengarten, JF .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) :2077-2087
[2]   Synthesis of fullerene-cardanol derivatives [J].
Attanasi, OA ;
Del Sole, R ;
Filippone, P ;
Ianne, R ;
Mazzetto, SE ;
Mele, G ;
Vasapollo, G .
SYNLETT, 2004, (05) :799-802
[3]   Fullerene-based amino acids and peptides [J].
Bianco, A ;
Da Ros, T ;
Prato, M ;
Toniolo, C .
JOURNAL OF PEPTIDE SCIENCE, 2001, 7 (04) :208-219
[4]   Solvent-free phase transfer catalysis under microwaves in fullerene chemistry. A convenient preparation of N-alkylpyrrolidino[60]fullerenes. [J].
de la Cruz, P ;
de la Hoz, A ;
Font, LM ;
Langa, F ;
Perez-Rodriguez, MC .
TETRAHEDRON LETTERS, 1998, 39 (33) :6053-6056
[5]   N-(2,4-dinitrophenyl)-2-phenylfulleropyrrolidine:: an electroactive organofullerene dyad [J].
Deviprasad, GR ;
Rahman, MS ;
D'Souza, F .
CHEMICAL COMMUNICATIONS, 1999, (09) :849-850
[6]   Ordering fullerene materials at manometer dimensions [J].
Guldi, DM ;
Zerbetto, F ;
Georgakilas, V ;
Prato, M .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (01) :38-43
[7]   Donor/acceptor fulleropyrrolidine triads [J].
Herranz, MA ;
Illescas, B ;
Martín, N ;
Luo, CP ;
Guldi, DM .
JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (18) :5728-5738
[8]  
HIRSCH A, 2005, FULLERENES CHEM REAC, P422
[9]   Helicity induction in hydrogen-bonding-driven zinc porphyrin foldamers by chiral C60-incorporating histidines [J].
Hou, JL ;
Yi, HP ;
Shao, XB ;
Li, C ;
Wu, ZQ ;
Jiang, XK ;
Wu, LZ ;
Tung, CH ;
Li, ZT .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (05) :796-800
[10]  
KADISH KM, 2000, FULLERENES CHEM PHYS, P968