Selective oxidation of sulfides to sulfoxides and sulfones at room temperature using H2O2 and a Mo(VI) salt as catalyst

被引：153
作者：
Jeyakumar, Kandasamy [1 ]
Chand, Dillip Kumar [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 27期
关键词：
D O I：
10.1016/j.tetlet.2006.04.153
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Selective oxidation of sulfides to sulfoxides and sulfones is achieved by H2O2 using MoO2Cl2 as the catalyst. Various substituted sulfides having functional groups Such as methyl, methoxy, bromo, nitro, alkene. alkyne, alcohol. ester, aldehyde and remarkably an oxime are successfully and selectively oxidized without affecting the sensitive functionalities. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4573 / 4576
页数：4
相关论文
共 42 条
  • [1] Selective oxidation of sulfides to sulfoxides and sulfones using hydrogen peroxide (H2O2) in the presence of zirconium tetrachloride
    Bahrami, K
    [J]. TETRAHEDRON LETTERS, 2006, 47 (12) : 2009 - 2012
  • [2] Synthesis of heteroaromatic analogues of (2-aryl-1-cyclopentenyl-1-alkylidene)-(arylmethyloxy)amine COX-2 inhibitors: effects on the inhibitory activity of the replacement of the cyclopentene central core with pyrazole, thiophene or isoxazole ring
    Balsamo, A
    Coletta, I
    Guglielmotti, A
    Landolfi, C
    Mancini, F
    Martinelli, A
    Milanese, C
    Minutolo, F
    Nencetti, S
    Orlandini, E
    Pinza, M
    Rapposelli, S
    Rossello, A
    [J]. EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2003, 38 (02) : 157 - 168
  • [3] OXIDATION OF ELECTRON-DEFICIENT SULFIDES TO SULFONES USING HOF.CH3CN
    BECKERBAUER, R
    SMART, BE
    BAREKET, Y
    ROZEN, S
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (19) : 6186 - 6187
  • [4] THE ORGANOSULFUR CHEMISTRY OF THE GENUS ALLIUM - IMPLICATIONS FOR THE ORGANIC-CHEMISTRY OF SULFUR
    BLOCK, E
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1992, 31 (09) : 1135 - 1178
  • [5] Regeneration of carbonyl compounds from oximes and hydrazones using peroxymonosulfate on silica gel under solvent-free conditions
    Bose, DS
    Narsaiah, AV
    Lakshminarayana, V
    [J]. SYNTHETIC COMMUNICATIONS, 2000, 30 (17) : 3121 - 3125
  • [6] Nucleophilic acyl substitutions of anhydrides with protic nucleophiles catalyzed by amphoteric, oxomolybdenum species
    Chen, CT
    Kuo, JH
    Pawar, VD
    Munot, YS
    Weng, SS
    Ku, CH
    Liu, CY
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (04) : 1188 - 1197
  • [7] DIRECT TRIFLUOROMETHYLTHIOLATION OF ARYL HALIDES USING METHYL FLUOROSULFONYLDIFLUOROACETATE AND SULFUR
    CHEN, QY
    DUAN, JX
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (11) : 918 - 919
  • [8] Selective oxidation of allylic sulfides by hydrogen peroxide with the trirutile-type solid oxide catalyst LiNbMoO6
    Choi, S
    Yang, JD
    Ji, M
    Choi, H
    Kee, M
    Ahn, KH
    Byeon, SH
    Baik, W
    Koo, S
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (24) : 8192 - 8198
  • [9] Tungstate-exchanged Mg-Al-LDH catalyst: an eco-compatible route for the oxidation of sulfides in aqueous medium
    Choudary, BM
    Bharathi, B
    Reddy, CV
    Kantam, ML
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2002, (18): : 2069 - 2074
  • [10] VO(acac)2 catalyzed oxidative deprotection of oximes, hydrazones, and semicarbazones
    De, SK
    [J]. SYNTHETIC COMMUNICATIONS, 2004, 34 (23) : 4409 - 4415
12345