An up-scalable approach to CH3NH3PbI3 compact films for high-performance perovskite solar cells

被引：76

作者：

Yang, Zhou ^{[1
]}

Cai, Bing ^{[1
,2
]}

Zhou, Bin ^{[1
]}

Yao, Tingting ^{[1
]}

Yu, Wei ^{[1
]}

Liu, Shengzhong ^{[1
,3
]}

Zhang, Wen-Hua ^{[1
]}

Li, Can ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China

[2] Dalian Univ Technol, Liaoning Key Lab Energy Mat & Chem Engn, State Key Lab Fine Chem, Carbon Res Lab, Dalian 116024, Peoples R China

[3] Shaanxi Normal Univ, Sch Mat Sci & Engn, Xian 710062, Peoples R China

来源：

NANO ENERGY | 2015年 / 15卷

关键词：

Perovskite; Film; Solar cells; Centimeter-scale uniformity; Up-scale; ORGANOLEAD HALIDE PEROVSKITE; HIGH-EFFICIENCY; HYSTERESIS; CRYSTALLIZATION; TRIHALIDE; BEHAVIOR;

D O I：

10.1016/j.nanoen.2015.05.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work, we describe an up-scalable, two step approach to prepare CH3NH3PbI3 perovskite films with high quality and exceptional uniformity at centimeter-scale (5.0 cm x 5.0 cm). The resulting solar cells achieve efficiency up to 16% with an average efficiency of 14.3% for small-area devices. Remarkably, devices with size of 1.0 cm x 1.0 cm made on the 5.0 cm x 5.0 cm perovskite films display a very impressive efficiency up to 12.6% with an average efficiency of 10.9% (for 48 devices), which is significantly superior to previous reports (<9.0% efficiency) with centimeter-sized devices. The present approach combines the advantages of the short reaction time, facile fabrication, exceptional uniformity, good reproducibility, high device performance and up-scalability, enabling it the potential ability in large-scale photovoltaic applications. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：670 / 678

页数：9

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