A robust porous material constructed of linear coordination polymer chains: Reversible single-crystal to single-crystal transformations upon dehydration and rehydration

被引：375

作者：

Lee, EY ^{[1
]}

Suh, MP ^{[1
]}

机构：

[1] Seoul Natl Univ, Sch Chem & Mol Engn, Seoul 151747, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 21期

关键词：

adsorption; coordination polymers; host-guest systems; microporous materials; nickel;

D O I：

10.1002/anie.200353494

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hole in one: A metal-organic framework with permanent microporosity has been constructed from linear coordination polymer chains consisting of Ni(cyclam)]2+ and bpydc2-. In framework 1 the chains run in three directions (red, green, blue in the picture) and are stacked to form 1D channels that are filled with water molecules, which can be removed completely and reabsorbed with retention of the single crystallinity.

引用

页码：2798 / 2801

页数：4

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