Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines

被引：153

作者：

Frogneux, Xavier ^{[1
]}

Jacquet, Olivier ^{[1
]}

Cantat, Thibault ^{[1
]}

机构：

[1] CEA Saclay, CEA, CNRS, IRAMIS,SIS2M,UMR 3299, F-91191 Gif Sur Yvette, France

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2014年 / 4卷 / 06期

基金：

欧洲研究理事会;

关键词：

CARBON-DIOXIDE; SELECTIVE REDUCTION; CARBOXYLIC-ACIDS; ESTERS; COMPLEXES; ALDEHYDES; AMINES; HYDROSILANES; METHANE; POLYMETHYLHYDROSILOXANE;

D O I：

10.1039/c4cy00130c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic hydrosilylation of CO2 is an efficient and selective approach to form chemicals. Herein, we describe the first iron catalysts able to promote the reductive functionalization of CO2 using hydrosilanes as reductants. Iron(II) salts supported by phosphine donors enable the conversion of CO2 to formamide and methylamine derivatives under mild reaction conditions.

引用

页码：1529 / 1533

页数：5

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