Ultra-Low Friction with a Protic Ionic Liquid Boundary Film at the Water-Lubricated Sapphire-Stainless Steel Interface

被引:103
作者
Espinosa, Tulia [1 ]
Jimenez, Miguel [1 ]
Sanes, Jose [1 ]
Jimenez, Ana-Eva [1 ]
Iglesias, Miguel [2 ]
Bermudez, Maria-Dolores [1 ]
机构
[1] Univ Politecn Cartagena, Grp Ciencia Mat & Ingn Met, Dept Ingn Mat & Fabricac, Cartagena 30202, Spain
[2] Univ Fed Bahia, Dept Engn Quim, Salvador, BA, Brazil
关键词
Protic ionic liquid; Water; Stainless steel; Sapphire; Friction; Wear; Boundary lubrication; Surface interactions; TRIBOLOGICAL BEHAVIOR; SURFACE INTERACTIONS; ADDITIVES; SALTS;
D O I
10.1007/s11249-013-0238-3
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The sapphire/AISI 316L contact has been lubricated with water, with the protic ionic liquid (PIL) bis (2-hydroxyethylammonium) succinate (MSu), and with a 1 wt% solution of MSu in water. Neat water evaporates after the running-in period to give a transition to dry contact. Neat MSu reduces the running-in period, reducing the friction coefficient to 0.09, an 88 % lower than water. Water + 1 wt% MSu reduces the running-in period, and after water evaporation, a PIL boundary film is formed, with an ultralow minimum friction coefficient of 0.0001, and a mean friction value of 0.02, a 97 % lower than that of water, and a 78 % lower than that of neat MSu. Surface interactions have been studied by 3D profilometry, FTIR, SEM-EDX, and XPS analysis.
引用
收藏
页码:1 / 9
页数:9
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