Ultra-Low Friction with a Protic Ionic Liquid Boundary Film at the Water-Lubricated Sapphire-Stainless Steel Interface

被引:103
作者
Espinosa, Tulia [1 ]
Jimenez, Miguel [1 ]
Sanes, Jose [1 ]
Jimenez, Ana-Eva [1 ]
Iglesias, Miguel [2 ]
Bermudez, Maria-Dolores [1 ]
机构
[1] Univ Politecn Cartagena, Grp Ciencia Mat & Ingn Met, Dept Ingn Mat & Fabricac, Cartagena 30202, Spain
[2] Univ Fed Bahia, Dept Engn Quim, Salvador, BA, Brazil
关键词
Protic ionic liquid; Water; Stainless steel; Sapphire; Friction; Wear; Boundary lubrication; Surface interactions; TRIBOLOGICAL BEHAVIOR; SURFACE INTERACTIONS; ADDITIVES; SALTS;
D O I
10.1007/s11249-013-0238-3
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The sapphire/AISI 316L contact has been lubricated with water, with the protic ionic liquid (PIL) bis (2-hydroxyethylammonium) succinate (MSu), and with a 1 wt% solution of MSu in water. Neat water evaporates after the running-in period to give a transition to dry contact. Neat MSu reduces the running-in period, reducing the friction coefficient to 0.09, an 88 % lower than water. Water + 1 wt% MSu reduces the running-in period, and after water evaporation, a PIL boundary film is formed, with an ultralow minimum friction coefficient of 0.0001, and a mean friction value of 0.02, a 97 % lower than that of water, and a 78 % lower than that of neat MSu. Surface interactions have been studied by 3D profilometry, FTIR, SEM-EDX, and XPS analysis.
引用
收藏
页码:1 / 9
页数:9
相关论文
共 47 条
[1]   Thermophysical properties of binary mixtures of {ionic liquid 2-hydroxy ethylammonium acetate plus (water, methanol, or ethanol)} [J].
Alvarez, Victor H. ;
Mattedi, Silvana ;
Martin-Pastor, Manuel ;
Aznar, Martin ;
Iglesias, Miguel .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2011, 43 (07) :997-1010
[2]   Synthesis and thermophysical properties of two new protic long-chain ionic liquids with the oleate anion [J].
Alvarez, Victor H. ;
Mattedi, Silvana ;
Martin-Pastor, Manuel ;
Aznar, Martin ;
Iglesias, Miguel .
FLUID PHASE EQUILIBRIA, 2010, 299 (01) :42-50
[3]   Ionic Liquids: Past, present and future [J].
Angell, C. Austen ;
Ansari, Younes ;
Zhao, Zuofeng .
FARADAY DISCUSSIONS, 2012, 154 :9-27
[4]  
[Anonymous], 2010, Tribology Letters, V40, P213
[5]  
[Anonymous], 1995, Handbook of X-ray Photoelectron Spectroscopy. A Reference Book of Standard Spectra for Identification and Interpretation of XPS Data
[6]   Ionic Liquid Nanotribology: Stiction Suppression and Surface Induced Shear Thinning [J].
Asencio, Ruben Alvarez ;
Cranston, Emily D. ;
Atkin, Rob ;
Rutland, Mark W. .
LANGMUIR, 2012, 28 (26) :9967-9976
[7]  
Bermudez M.D., 2011, Patent, Patent No. [ES 2373298, 2373298]
[8]   Introduction to the Ionic Liquids Special Issue [J].
Bermudez, Maria-Dolores .
TRIBOLOGY LETTERS, 2010, 40 (02) :213-213
[9]   Ionic Liquids as Advanced Lubricant Fluids [J].
Bermudez, Maria-Dolores ;
Jimenez, Ana-Eva ;
Sanes, Jose ;
Carrion, Francisco-Jose .
MOLECULES, 2009, 14 (08) :2888-2908
[10]   Temperature distribution over contact area and "hot spots" in rubbing solid contact [J].
Bogdanovich, P. N. ;
Tkachuk, D. V. .
TRIBOLOGY INTERNATIONAL, 2006, 39 (11) :1355-1360