An Amine-Functionalized MIL-53 Metal-Organic Framework with Large Separation Power for CO2 and CH4

被引：913

作者：

Couck, Sarah ^{[1
]}

Denayer, Joeri F. M. ^{[1
]}

Baron, Gino V. ^{[1
]}

Remy, Tom ^{[1
]}

Gascon, Jorge ^{[2
]}

Kapteijn, Freek ^{[2
]}

机构：

[1] Vrije Univ Brussels, Dept Chem Engn, Brussels, Belgium

[2] Delft Univ Technol, NL-2600 AA Delft, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 18期

关键词：

CARBON-DIOXIDE; TEREPHTHALATE MIL-53; HIGH-CAPACITY; PORE-SIZE; ADSORPTION; CAPTURE; METHANE; STORAGE; TEMPERATURE; ADSORBENT;

D O I：

10.1021/ja900555r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Functionalizing the well-known MIL-53(Al) metal-organic framework with amino groups increases its selectivity in CO2/CH4 separations by orders of magnitude while maintaining a very high capacity for CO2 capture.

引用

页码：6326 / +

页数：3

共 31 条

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