Multivariate approach to the photo-Fenton process applied to the degradation of winery wastewaters

被引：54

作者：

Ormad, Maria P. ^{[1
]}

Mosteo, Rosa ^{[1
]}

Ibarz, Cristina ^{[1
]}

Ovelleiro, Jose L. ^{[1
]}

机构：

[1] Univ Zaragoza, Ctr Politecn Super, Dept Ingn Quim & Tecnol Medio Ambiente, Zaragoza 50018, Spain

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2006年 / 66卷 / 1-2期

关键词：

winery wastewaters; experimental design; multivariate analysis; photo-Fenton processes;

D O I：

10.1016/j.apcatb.2006.02.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Winery wastewaters, being seasonal and experiencing substantial flow variations, are difficult to treat by conventional biological processes. This work proposes the photo-Fenton reaction in homogeneous phase as an alternative for their purification. Experimental design methodology has been used in order to study the main variables affecting the oxidation process as well as their most relevant interactions. Under energetic conditions the photo-Fenton treatment reached purification levels of up to 95% (measured as total organic carbon). The most influential factors behind organic matter removal are the Fe3(+) and H2O2 dosage. The influence of the initial organic matter concentration and the reaction time is almost negligible for the confidence level selected (90%) in the results analysis. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：58 / 63

页数：6

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