Sequential self-assembly of calix[4]resorcinarene-based heterobimetallic Cd8Pt8 nano-Saturn complexes

被引:0
|
作者
He, Lipeng [1 ,2 ]
Li, Lijie [1 ,3 ]
Wang, Shi-Cheng [1 ]
Chan, Yi-Tsu [1 ]
机构
[1] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan
[2] Lanzhou Univ, Coll Chem & Chem Engn, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Peoples R China
[3] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A rational molecular design strategy is introduced for selective metal-ligand coordination, enabling the quantitative self-assembly of heterobimetallic nano-Saturn complexes. During the sequential multicomponent self-assembly, the CdII ions and organometallic trans-PtII motifs demonstrate preferential binding to specific ligands. The pre-designed directive interactions allow for precise control over the structural characteristics.
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页数:4
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