Kinetics of water oxidation with cerium(IV) compounds catalyzed by a tetranuclear ruthenium complex

被引：5

作者：

Dzhabieva, Z. M. ^{[1
]}

Yakutkina, O. V. ^{[1
]}

Dzhabiev, T. S. ^{[1
]}

Shilov, A. E. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia

来源：

KINETICS AND CATALYSIS | 2014年 / 55卷 / 04期

关键词：

POLYOXOMETALATE; LIGANDS;

D O I：

10.1134/S002315841404003X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics and mechanism of water oxidation with cerium(IV) compounds catalyzed by a tetranuclear ruthenium complex containing two polyoxotungstate ligands are reported. Four water molecules are oxidized via an eight-electron process to form two oxygen molecules.

引用

页码：422 / 427

页数：6

共 22 条

[1] Cs9[(γ-PW10O36)2Ru4O5(OH)(H2O)4], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water [J].

Besson, Claire ;

Huang, Zhuangqun ;

Geletii, Yurii V. ;

Lense, Sheri ;

Hardcastle, Kenneth I. ;

Musaev, Djamaladdin G. ;

Lian, Tianquan ;

Proust, Anna ;

Hill, Craig L. .

CHEMICAL COMMUNICATIONS, 2010, 46 (16) :2784-2786

[2] The Ru-Hbpp Water Oxidation Catalyst [J].

Bozoglian, Fernando ;

Romain, Sophie ;

Ertem, Mehmed Z. ;

Todorova, Tanya K. ;

Sens, Cristina ;

Mola, Joaquim ;

Rodriguez, Montserrat ;

Romero, Isabel ;

Benet-Buchholz, Jordi ;

Fontrodona, Xavier ;

Cramer, Christopher J. ;

Gagliardi, Laura ;

Llobet, Antoni .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (42) :15176-15187

[3]

Cacace F, 2001, ANGEW CHEM INT EDIT, V40, P4062, DOI 10.1002/1521-3773(20011105)40:21<4062::AID-ANIE4062>3.0.CO

[4]

2-X

[5] Structurally Characterized Iridium(III)-Containing Polytungstate and Catalytic Water Oxidation Activity [J].

Cao, Rui ;

Ma, Huiyuan ;

Geletii, Yurii V. ;

Hardcastle, Kenneth I. ;

Hill, Craig L. .

INORGANIC CHEMISTRY, 2009, 48 (13) :5596-5598

[6] One Site is Enough. Catalytic Water Oxidation by [Ru(tpy)(bpm)(OH2)]2+ and [Ru(tpy)(bpz)(OH2)]2+ [J].

Concepcion, Javier J. ;

Jurss, Jonah W. ;

Templeton, Joseph L. ;

Meyer, Thomas J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (49) :16462-+

[7] Biomimetic utilization of solar energy [J].

Dzhabiev, T. S. ;

Shilov, A. E. .

RUSSIAN CHEMICAL REVIEWS, 2012, 81 (12) :1146-1158

[8] An all-inorganic, stable, and highly active tetraruthenium homogeneous catalyst for water oxidation [J].

Geletii, Yurii V. ;

Botar, Bogdan ;

Koegerler, Paul ;

Hillesheim, Daniel A. ;

Musaev, Djamaladdin G. ;

Hill, Craig L. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (21) :3896-3899

[9] Homogeneous Light-Driven Water Oxidation Catalyzed by a Tetraruthenium Complex with All Inorganic Ligands [J].

Geletii, Yurii V. ;

Huang, Zhuangqun ;

Hou, Yu ;

Musaev, Djamaladdin G. ;

Lian, Tianquan ;

Hill, Craig L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (22) :7522-+

[10] A diruthenium-substituted polyoxometalate as an electrocatalyst for oxygen generation [J].

Howells, AR ;

Sankarraj, A ;

Shannon, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (39) :12258-12259

← 1 2 3 →