Structural analysis of La-Mg-Ni-based new hydrogen storage alloy

被引：3

作者：

Kohno, T.

Takeno, S.

Yoshida, H.

Kanda, M.

机构：

[1] Toshiba Co Ltd, Ctr Corp Res & Dev, Adv Funct Mat Lab, Saiwai Ku, Kanagawa 2128582, Japan

[2] Toshiba Co Ltd, Ctr Corp Res & Dev, Adv LSI Technol Lab, Saiwai Ku, Kanagawa 2128582, Japan

[3] Japan Sci & Technol Corp, Chiyoda Ku, Tokyo 1028666, Japan

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2006年 / 32卷 / 5-6期

关键词：

structure analysis; La5Mg2Ni23; alloy; La3MgNi14;

D O I：

10.1163/156856706777973790

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structural analysis of new hydrogen storage alloys, La5Mg2Ni23 and La(3)MgNi1(4,) was performed using HRTEM. As a result, these ternary system alloys were found to be mainly composed of stacked RNi5 (CaCu type) and R2Ni4 (Laves type) structure subunits in a superstructure arrangement. La5Mg2Ni23 alloy is composed of the primitive cell of three LaNi5 units and the primitive cell of two La2Mg2Ni4 units. La3MgNi14 alloy is composed of four LaNi5 and two La2Mg2Ni4 unit cells.

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页码：437 / 445

页数：9

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