Access to 2-naphthols via Ru(ii)-catalyzed C-H annulation of nitrones with α-diazo sulfonyl ketones

被引：21
|
作者：
Kong, Lingheng [1 ]
Han, Xi [1 ]
Li, Xingwei [1 ]
机构：
[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Appl Surface & Colloid Chem MOE, Xian 710062, Shaanxi, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 51期
关键词：
RH(III)-CATALYZED SYNTHESIS; DIVERGENT COUPLINGS; CATALYZED SYNTHESIS; SULFOXONIUM YLIDES; BOND ACTIVATION; FUNCTIONALIZATION; CYCLIZATION; BENZAMIDES; ACTIVATION/CYCLIZATION; ISOQUINOLINES;
D O I：
10.1039/c9cc02949d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Efficient synthesis of 2-naphthols was realized by Ru(ii)-catalyzed C-H activation of aryl nitrones and intermolecular [3+3] annulation with alpha-diazo sulfonyl ketones under redox-neutral conditions. Easily available alpha-diazo sulfonyl ketones act as a three-carbon component in the reaction.
引用
收藏
页码：7339 / 7342
页数：4
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