Three-phase polymer-ceramic-metal composite for embedded capacitor applications

被引:78
作者
George, Sumesh [1 ]
Sebastian, Mailadil Thomas [1 ]
机构
[1] Natl Inst Interdisciplinary Sci & Technol, Mat & Minerals Div, Trivandrum 695019, Kerala, India
关键词
Polymer-matrix composites; Electrical properties; Optical microscopy; High permittivity; Embedded passives; EFFECTIVE DIELECTRIC-CONSTANT; PERCOLATION; BEHAVIOR; PERMITTIVITY; TEMPERATURE;
D O I
10.1016/j.compscitech.2009.03.003
中图分类号
TB33 [复合材料];
学科分类号
摘要
This paper addresses the materials and processes for printed wiring board compatible embedded capacitor using ceramic, polymer and metal. The Ca[(Li1/3Nb2/3)(0.8)Ti-0.2]O3-delta (CLNT)-epoxy-silver, three-phase composites were prepared by two step mixing and thermosetting technique. The dielectric properties of the three-phase composites were investigated in terms of volume fraction of silver, temperature and frequency. The dielectric properties of epoxy-CLNT composites were compared with theoretical predictions. The relative permittivity of the three-phase composites increased with silver loading. Addition of 0.28 volume fraction of silver increases the relative permittivity of epoxy-CLNT composites from 8 to 142 at 1 MHz. This composite is flexible and can be fabricated into various shapes with low processing temperature. (c) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1298 / 1302
页数:5
相关论文
共 43 条
[1]   High-dielectric-constant ceramic-powder polymer composites [J].
Bai, Y ;
Cheng, ZY ;
Bharti, V ;
Xu, HS ;
Zhang, QM .
APPLIED PHYSICS LETTERS, 2000, 76 (25) :3804-3806
[2]   Next generation integral passives: materials, processes, and integration of resistors and capacitors on PWB substrates [J].
Bhattacharya, SK ;
Tummala, RR .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2000, 11 (03) :253-268
[3]   DIELECTRIC-PROPERTIES OF POLYMERS AT MICROWAVE-FREQUENCIES - A REVIEW [J].
BUR, AJ .
POLYMER, 1985, 26 (07) :963-977
[4]   Organic thin-film transistors with nanocomposite dielectric gate insulator [J].
Chen, FC ;
Chu, CW ;
He, J ;
Yang, Y ;
Lin, JL .
APPLIED PHYSICS LETTERS, 2004, 85 (15) :3295-3297
[5]   Effect of silver addition on the dielectric properties of barium titanate-based X7R ceramics [J].
Chen, RZ ;
Wang, XH ;
Gui, ZL ;
Li, LT .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2003, 86 (06) :1022-1024
[6]   Effects of BaTiO3 on dielectric behavior of BaTiO3-Ni-polymethyl methacrylate composites [J].
Choi, Hyung-Woo ;
Heo, Young-Woo ;
Lee, Joon-Hyung ;
Kim, Jeong-Joo ;
Lee, Hee-Young ;
Park, Eun-Tae ;
Chung, Yul-Kyo .
APPLIED PHYSICS LETTERS, 2006, 89 (13)
[7]   Microwave dielectric properties of Ca[(Li1/3Nb2/3)1-xMx]O3-δ (M = Sn, Ti) ceramics [J].
Choi, JW ;
Kang, CY ;
Yoon, SJ ;
Kim, HJ ;
Jung, HJ ;
Yeon, KH .
JOURNAL OF MATERIALS RESEARCH, 1999, 14 (09) :3567-3570
[8]   EFFECTIVE DIELECTRIC-CONSTANT OF A METAL-DIELECTRIC COMPOSITE [J].
CHYLEK, P ;
SRIVASTAVA, V .
PHYSICAL REVIEW B, 1984, 30 (02) :1008-1009
[9]   Novel ferroelectric polymer composites with high dielectric constants [J].
Dang, ZM ;
Lin, YH ;
Nan, CW .
ADVANCED MATERIALS, 2003, 15 (19) :1625-+
[10]   Dielectric behavior of three-phase percolative Ni-BaTiO3/polyvinylidene fluoride composites [J].
Dang, ZM ;
Shen, Y ;
Nan, CW .
APPLIED PHYSICS LETTERS, 2002, 81 (25) :4814-4816