A catalytic, environmentally benign method for the epoxidation of unsaturated terpenes with hydrogen peroxide

被引：33

作者：

Grigoropoulou, Georgia ^{[1
]}

Clark, James H. ^{[1
]}

机构：

[1] Univ York, Ctr Clean Technol, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 26期

关键词：

D O I：

10.1016/j.tetlet.2006.04.047

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various unsaturated terpenes were selectively oxidised to the corresponding epoxides in good yields using phosphate buffered hydrogen peroxide and catalytic amounts of tungstate Under halide free conditions. The selectivity of the reaction to epoxides was significantly increased with respect to the ionic strength of the aqueous phase of the system. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：4461 / 4463

页数：3

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