Eco-friendly and recyclable media for rapid synthesis of tricyanovinylated aromatics using biocatalyst and deep eutectic solvent

被引：40

作者：

Sanap, Anita Kailas ^{[1
]}

Shankarling, Ganapati Subray ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Dyestuff Technol, Bombay 400019, Maharashtra, India

来源：

CATALYSIS COMMUNICATIONS | 2014年 / 49卷

关键词：

Tricyanovinylation; Protease enzyme; Deep eutectic solvent; Lipase enzyme; Solvatochromism;

D O I：

10.1016/j.catcom.2014.01.031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An efficient and clean synthesis of aromatic tricyanovinyl compounds from nucleophilic reagent and tetracyanoethylene has been achieved using biocatalyst and deep eutectic solvent (DES). Reaction using biocatalyst and DES requires lesser reaction time than conventional method. The advantages of the present method are ambient reaction temperature, easy isolation of the product, higher yield, recyclability of the catalyst, and reactions without use of hazardous, volatile organic solvent. The DES as well as biocatalyst were recycled efficiently without any additional treatment. Synthesized compounds were also studied for UV-vis absorption and show solvatochromism. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：58 / 62

页数：5

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