Extraction of Copper(II) from Weakly Acid and Ammonia Media with N′,N′-Dialkylhydrazides of Aliphatic Carboxylic Acids

被引:1
作者
Batueva, T. D. [1 ]
Radushev, A. V. [1 ]
Gusev, V. Yu. [1 ]
机构
[1] Russian Acad Sci, Inst Tech Chem, Perm, Russia
基金
俄罗斯基础研究基金会;
关键词
SOLVENT-EXTRACTION;
D O I
10.1134/S1070427209110172
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Dependence of physicochemical properties of N',N'-dialkylhydrazides of aliphatic carboxylic acids (solubility in kerosene, acid-base properties) on the length of hydrocarbon radicals in the functional group was studied. The extraction capacity for copper(II) salts in weakly acid and ammonia media was examined in the range from pH 5-11 to a NH3 content of 2.7 M. The capacity of the organic phase for copper(II) and re-extraction conditions were determined for the example of N',N'-dibutylhydrazide of octanoic acid.
引用
收藏
页码:1997 / 2001
页数:5
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