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Effective photocatalytic decolorization of indigo carmine dye in Moroccan natural phosphate-TiO2 aqueous suspensions
被引:12
作者:
Naciri, Nouama
[1
]
Farahi, Abdelfettah
[1
,2
]
Rafqah, Salah
[3
]
Nasrellah, Hamid
[1
]
El Mhammedi, Moulay Abderrahim
[2
]
Lancar, IbnToumaret
[1
]
Bakasse, Mina
[1
]
机构:
[1] Univ Chouaib Doukkali, Fac Sci, Lab Chem Organ Bioorgan & Environm, El Jadida, Morocco
[2] Univ Hassan 1er Khouribga, Fac Polydisciplinairy, Lab Chem & Math Modelling, Marrakech, Morocco
[3] Univ Cadi Ayyad, Fac Polydisciplinairy SAFI, Lab Analyt Chem & Mol, Marrakech, Morocco
来源:
关键词:
Photocatalysis;
Decolorization;
Natural phosphate;
Titanium dioxide;
Indigo carmine;
TERM TOXICITY;
WASTE-WATER;
DEGRADATION;
ADSORPTION;
TIO2;
EFFLUENTS;
INDUSTRY;
REMOVAL;
IONS;
D O I:
10.1016/j.optmat.2015.12.011
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
Heterogeneous photocatalysis is a significant green technology for application in water purification. In this study, the photocatalytic activity of NP-TiO2 based on Moroccan natural phosphate (NP) doped by titanium dioxide TiO2 was evaluated by photocatalytic decolorization of indigo carmine (IC) dye in aqueous solution as a model pollutant under UV light. The NP-TiO2 catalyst was characterized by XRD, FTIR and surface area. The effect of the calcination temperature of NP-TiO2, catalyst concentration, initial concentration of the IC, initial pH, initial hydrogen peroxide H2O2 concentration and coexisting ions on the photocatalytic decolorization of IC was investigated. The NP-TiO2 showed a significantly higher rate of degradation of IC, when compared to TiO2. After 125 min of irradiation using a low intensity of UV-lamp (15 W * 3 lamps = 45 W), 99% of IC solution (20 mg L-1) was decolorized with 0.5 g L-1 of the NP-TiO2 calcined at 600 degrees C at pH = 11. Therefore, this process can be developed as an economically feasible and environmentally friendly method to decolorize or treat dye wastewater using sunlight. (C) 2015 Elsevier B.V. All rights reserved.
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页码:38 / 43
页数:6
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