(2,2′-Bipyridine-κ2N,N′){N-[2-oxido-5-(phenyldiazenyl)benzylidene-κO]glycinato-κ2N,O}copper(II)

被引：2

作者：

Zhang, Qiu-Xia ^{[1
]}

Zhao, Gan-Qing ^{[1
]}

Zhu, Jian-Qi ^{[1
]}

Xue, Ling-Wei ^{[1
]}

Han, Yong-Jun ^{[1
]}

机构：

[1] Pingdingshan Univ, Sch Chem & Chem Engn, Pingdingshan 467000, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

COPPER(II); COMPLEXES;

D O I：

10.1107/S1600536809036423

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Cu(C15H11N3O3)(C10H8N2)], the Cu-II atom is five-coordinated in a distorted square-pyramidal CuN3O2 geometry. The basal positions are occupied by three donor atoms from the tridentate Schiff base ligand and by one N atom from the 2,2'-bipyridine ligand. The axial position is occupied by the other N atom of the 2,2'-bipyridine ligand. The crystal structure is consolidated by weak C-H center dot center dot center dot O hydrogen bonds. In addition, pi-pi interactions between adjacent pyridine rings (centroid-centroid distances = 3.238 and 3.313 angstrom) may also stabilize the crystal packing.

引用

页码：M1212 / +

页数：11

共 13 条

[1] [Anonymous], 2008, APEX2 SAINT
[2] Crystal structures of the N-salicylidene-L-serinatoaquacopper(II) monohydrate and its ternary derivative with 2-aminopyridine
García-Raso, A
Fiol, JJ
López-Zafra, A
Cabrero, A
Mata, I
Molins, E
[J]. POLYHEDRON, 1999, 18 (06) : 871 - 878
[3] Coordination geometries and cooperative ordering effects in copper(II) complexes with tridentate Schiff base dianions .5. Epr spectra of [N-salicylidene-(R,S)-alaninato]copper(II) complexes with derivatives of imidazole and pyrazole and structure of 1-methylimidazole[N-salicylidene-(R,S)-valinato]copper(II)
Plesch, G
Friebel, C
Warda, SA
Sivy, J
Svajlenova, O
[J]. TRANSITION METAL CHEMISTRY, 1997, 22 (05) : 433 - 440
[4] RASO AG, 1996, POLYHEDRON, V18, P4407
[5] Synthesis, crystal structures and properties of ternary copper(II) complexes having 2,2′-bipyridine and α-amino acid salicylaldiminates as models for the type-2 sites in copper oxidases
Reddy, PAN
Nethaji, M
Chakravarty, AR
[J]. INORGANICA CHIMICA ACTA, 2002, 337 : 450 - 458
[6] Sheldrick G.M., 1996, SADABS
[7] A short history of SHELX
Sheldrick, George M.
[J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
[8] The synthesis and crystal structure of one novel ternary complex of 2,2'-bipyridine N-salicylidenetyrosinatocopper(II)
Wang, MZ
Cai, GL
Meng, ZX
Liu, BL
[J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2005, 35 (01) : 43 - 47
[9] Aqua(2-methylpyridine-N)(N-salicylidene-glycinato-O,N,O′)copper(II)
Warda, SA
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 1754 - 1755
[10] Bis(3,5-dimethylpyrazole-N2)(N-salicylideneglycinato-O,N,O′)copper(II)
Warda, SA
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 1759 - 1761

← 1 2 →