Optical and morphological modifications in post-thermally treated tris(8-hydroxyquinoline) gallium films deposited on quartz substrates

被引:20
作者
Muhammad, Fahmi Fariq [1 ]
Sulaiman, Khaulah
机构
[1] Koya Univ, Fac Sci & Hlth, Dept Phys, Koya, Kurdistan Regio, Iraq
关键词
Organometallic compounds; Annealing; Electron microscopy; X-ray tomography; THIN-FILMS; ALQ(3); PHOTOLUMINESCENCE; EFFICIENCY; STABILITY; LAYERS; GA;
D O I
10.1016/j.matchemphys.2014.08.017
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This work reports the optical and morphological modifications in vacuum deposited Gaq3 films upon thermal annealing. The annealing process has been carried out under flowing nitrogen gas for 10 min. It was noticed from the results that at 235 degrees C a broad absorption spectrum and increased photoluminescence to five times stronger than that of pristine film was achieved. Scanning electron microscopy and X-ray diffraction techniques ascertained morphological changes towards the formation of amorphous nanorods. The improvement in optical properties of Gaq3 films was found to be resulted from this morphological modification. The nanostructure formation was seen to be a viable method to enhance the morpho-optical properties of Gaq3 films, making Gaq3 a promising candidate for the application in organic electronics technology. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:473 / 477
页数:5
相关论文
共 25 条
[1]   Rayleigh scattering and luminescence blue shift in tris(8-hydroxyquinoline)aluminum films [J].
Auzel, F ;
Baldacchini, G ;
Baldacchini, T ;
Chlacchiaretta, P ;
Pode, RB .
JOURNAL OF LUMINESCENCE, 2006, 119 :111-115
[2]   Correlation between molecular packing and optical properties in different crystalline polymorphs and amorphous thin films of mer-tris(8-hydroxyquinoline)aluminum(III) [J].
Brinkmann, M ;
Gadret, G ;
Muccini, M ;
Taliani, C ;
Masciocchi, N ;
Sironi, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (21) :5147-5157
[3]   Growth of AlQ3 nanowires directly from amorphous thin film and nanoparticles [J].
Cho, Chun-Pei ;
Yu, Chung-Yi ;
Perng, Tsong-Pyng .
NANOTECHNOLOGY, 2006, 17 (21) :5506-5510
[4]   Near-field scanning optical microscopy of temperature- and thickness-dependent morphology and fluorescence in Alq3 films [J].
Credo, GM ;
Winn, DL ;
Buratto, SK .
CHEMISTRY OF MATERIALS, 2001, 13 (04) :1258-1265
[5]   Influence of atmospheric exposure of tris (8-hydroxyquinoline) aluminum (Alq3):: a photoluminescence and absorption study [J].
Djurisic, AB ;
Lau, TW ;
Lam, LSM ;
Chan, WK .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2004, 78 (03) :375-380
[6]   Molecular geometry, electronic structure and optical properties study of meridianal tris(8-hydroxyquinolinato)gallium(III) with ab initio and DFT methods [J].
Gahungu, G ;
Zhang, JP .
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2005, 755 (1-3) :19-30
[7]   Spectroscopic study of Mq3 (M = Al, Ga, In, q=8-hydroxyquinolinate) at high pressure [J].
Hernandez, I. ;
Gillin, W. P. ;
Somerton, M. .
JOURNAL OF LUMINESCENCE, 2009, 129 (12) :1835-1839
[8]   Influence of High Hydrostatic Pressure on Alq3, Gaq3, and Inq3 (q=8-Hydroxyquinoline) [J].
Hernandez, Ignacio ;
Gillin, William P. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (43) :14079-14086
[9]   Thermal and morphological effects on the hydrolytic stability of aluminum tris(8-hydroxyquinoline) (Alq3) [J].
Higginson, KA ;
Zhang, XM ;
Papadimitrakopoulos, F .
CHEMISTRY OF MATERIALS, 1998, 10 (04) :1017-1020
[10]   Improved efficiency of organic photovoltaic cells using tris (8-hydroxy-quinoline) aluminum as a doping material [J].
Kao, Po-Ching ;
Chu, Sheng-Yuan ;
Huang, Hsin-Hsuan ;
Tseng, Zong-Liang ;
Chen, Yu-Cheng .
THIN SOLID FILMS, 2009, 517 (17) :5301-5304