Iron-Catalyzed π-Activated C-O Ether Bond Cleavage with C-C and C-H Bond Formation

被引：24

作者：

Fan, Xiaohui ^{[1
,2
]}

Cui, Xiao-Meng ^{[1
]}

Guan, Yong-Hong ^{[1
]}

Fu, Lin-An ^{[1
]}

Lv, Hao ^{[1
]}

Guo, Kun ^{[1
]}

Zhu, Hong-Bo ^{[1
]}

机构：

[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China

[2] BNLMS, Beijing 100190, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 2014卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Synthetic methods; Allylation; C-O activation; C-C coupling; Hydrogen transfer; Iron; CARBON-CARBON BONDS; BENZYLIC ALCOHOLS; OXYGEN BOND; ALLYLATION; NUCLEOPHILES; REAGENTS; ALKYLATION; ALDEHYDES; EFFICIENT; ARENES;

D O I：

10.1002/ejoc.201301372

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel and efficient allylic alkylation reaction between -activated ethers and allylsilane was realized under mild conditions through iron(III)-catalyzed Csp3-O ether bond cleavage. The present protocol provides an attractive approach for the construction of sp(3)-sp(3) C-C bonds and can be potentially applied for the selective reduction of benzyl and allyl ethers to their corresponding hydrocarbon compounds by using triethylsilane as a hydride-transfer reagent.

引用

页码：498 / 501

页数：4

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