Quadratic hyperpolarizability of push-pull polyenes: A two-form analysis of the length effect

被引:7
作者
Barzoukas, M [1 ]
Fort, A [1 ]
BlanchardDesce, M [1 ]
机构
[1] ECOLE NORMALE SUPER,DEPT CHIM,URA 1679,F-75231 PARIS 05,FRANCE
关键词
quadratic hyperpolarizability; push-pull polyene;
D O I
10.1016/S0379-6779(97)80085-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present a two-form two-state description that generalizes to all push-pull molecules the bond length alternation (BLA) approach. All relevant parameters in our model can be derived from electrooptical absorption measurements. Within this framework, we analyse the length effect on the quadratic hyperpolarizability in two series of push-pull polyenes.
引用
收藏
页码:277 / 280
页数:4
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