Controlled Synthesis of NixCoyS4/rGO Composites for Constructing High-Performance Asymmetric Supercapacitor

被引:22
作者
Dong, Mingxia [1 ]
Wang, Zhixing [1 ]
Wang, Jiexi [1 ]
Guo, Huajun [1 ]
Li, Xinhai [1 ]
Yan, Guochun [1 ]
机构
[1] Cent S Univ, Sch Met & Environm, Changsha, Hunan, Peoples R China
基金
美国国家科学基金会;
关键词
nickel-cobalt sulfides; in-situ growth; high energy density; asymmetric supercapacitor; high cyclic stability; REDUCED GRAPHENE OXIDE; ELECTROCHEMICAL PERFORMANCE; NICO2S4; NANOPARTICLES; ELECTRODE MATERIALS; FACILE SYNTHESIS; CATHODE MATERIAL; NI FOAM; SPHERES; ARRAYS; FIBER;
D O I
10.3389/fmats.2019.00176
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nickel-cobalt sulfides (NixCoyS4) are promising supercapacitor materials due to their high capacitance, while the sluggish kinetics in terms of charge transfer limits their energy density. To achieve both high energy and power density for the NixCoyS4-based supercapacitor, sulfur-doped reduced graphene oxide (rGO) is incorporated into NixCoyS4 by an in situ growth-ion exchange strategy to synthesize NixCoyS4/rGO composites. Profited from the synergetic effect between rGO and NixCoyS4, the Ni1.64Co2.40S4/rGO electrode delivers high specific capacitance of 1,089 F g(-1) at 1 A g(-1), and remains 92.6% of its original capacitance at 20A g(-1) (1,008 F g(-1)). Asymmetric supercapacitors assembled with active carbon (AC) and Ni1.64Co2.40S4/(Ni1.64Co2.40S4/rGOHAC) offer both high specific capacitance (265.5 F g(-1) at 1 A g(-1)) and superior rate capability at 50 A g(-1) (recovering 63.6% of the capacitance determined at 1 A g(-1)). In addition, the assembled device exhibits a high capacitance retention of 92.6% after 10,000 cycles at 10A g(-1), which implies an excellent cyclic stability. Ragone plot reveals that the energy density of Ni1.64Co2.40S4/rGO//AC asymmetric supercapacitor do not vanish as it delivers 30.4 Wh kg(-1) at 10 kW kg(-1), demonstrating its promising application.
引用
收藏
页数:11
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