Mapping potential energy surfaces by core electron excitation:: the resonant Auger decay spectrum of BF3

被引：26

作者：

Miron, C

Feifel, R

Björneholm, O

Svensson, S

de Brito, AN

Sorensen, SL

Piancastelli, MN

Simon, M

Morin, P

机构：

[1] Univ Uppsala, Dept Phys, S-75121 Uppsala, Sweden

[2] Lab Nacl Luz Sincrotron, BR-13084971 Campinas, SP, Brazil

[3] Lund Univ, Dept Synchrotron Radiat Res, S-22100 Lund, Sweden

[4] Univ Roma Tor Vergata, Dept Chem Sci & Technol, I-00133 Rome, Italy

[5] Univ Paris 11, Lab LURE, F-91898 Orsay, France

[6] SPAM,DRECAM,DSM, CNRS, URA 2453, Lab Francis Perrin, F-91191 Gif Sur Yvette, France

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 359卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(02)00627-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

High-resolution electron spectroscopy applied under resonant Auger-Raman conditions is shown to be a powerful tool for characterizing complex potential energy surfaces of core-excited states in polyatomic systems. BF3 is used as a prototype molecule: excitation of the Bls --> 2a(2)(") transition leads to an exceptional out-of-plane vibrational excitation resolved over a wide energy range (3.6 eV). The photon energy dependence of the spectra through the resonance profile is rationalized in the frame of the relative slopes of the potential energy curves along the boron out-of-plane displacement coordinate. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：48 / 54

页数：7

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