μ-oxalato-bis[(2,2′-bipyridine)(N,N-dimethylformamide)copper(II)] bis(perchlorate)

被引:4
作者
Zhang, GL [1 ]
Li, YT [1 ]
Wu, ZY [1 ]
机构
[1] Ocean Univ China, Marine Drug & Food Inst, Qingdao 266003, Peoples R China
关键词
D O I
10.1107/S1600536806015030
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cu-2(C2O4)(C10H8N2)(2)(C3H7NO)(2)](ClO4)(2), the oxalate-bridged binuclear copper(II) complex cation is centrosymmetric. The Cu-II atom has a distorted square-pyramidal geometry with two O and two N atoms from oxalate and bipyridine ligands in the basal plane, and with a dimethylformamide O atom in the apical position. The Cu center dot center dot center dot Cu distance is 5.1492 (18) angstrom.
引用
收藏
页码:M1175 / M1177
页数:3
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