Multiporphyrinic Cages: Architectures and Functions

被引：250

作者：

Durot, Stephanie ^{[1
]}

Taesch, Julien ^{[1
]}

Heitz, Valerie ^{[1
]}

机构：

[1] CNRS UMR 7177, Inst Chim Strasbourg, Lab Synth Assemblages Mol Multifonct, F-67000 Strasbourg, France

来源：

CHEMICAL REVIEWS | 2014年 / 114卷 / 17期

关键词：

TEMPLATE-DIRECTED SYNTHESIS; SUPRAMOLECULAR COORDINATION CHEMISTRY; ARTIFICIAL PHOTOSYNTHETIC ANTENNA; RAY STRUCTURAL-CHARACTERIZATION; PHOTOINDUCED CHARGE SEPARATION; COFACIAL PORPHYRIN COMPLEXES; TRANSITION-METAL CATALYSTS; DOUBLE-DECKER PORPHYRIN; PI-PI INTERACTIONS; ELECTRON-TRANSFER;

D O I：

10.1021/cr400673y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview of the synthesis and applications of molecular containers containing more than one porphyrin in their framework and enclosing a three-dimensional (3D) cavity is presented. Multiporphyrinic molecular cages held together by more than two linkers are considered in the review, as these multiple linkers restrict or prevent free rotation of the porphyrin derivatives and in such molecular architectures an internal 3D void space exists. The synthesis of covalent multiporphyrinic cages requires an important effort in the case of a stepwise synthesis which starts with the preparation of a functionalized porphyrin ready to cyclize.

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收藏

页码：8542 / 8578

页数：37

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