Modern Microwave Methods in Solid-State Inorganic Materials Chemistry: From Fundamentals to Manufacturing

被引:384
作者
Kitchen, Helen J. [1 ]
Vallance, Simon K. [1 ,2 ]
Kennedy, Jennifer L. [1 ,3 ]
Tapia-Ruiz, Nuria [1 ]
Carassiti, Lucia [1 ]
Harrison, Andrew [4 ]
Whittaker, A. Gavin [5 ]
Drysdale, Timothy D. [3 ]
Kingman, Samuel W. [2 ]
Gregory, Duncan H. [1 ]
机构
[1] Univ Glasgow, Sch Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland
[2] Univ Nottingham, Dept Chem & Environm Engn, Nottingham NG7 2RD, England
[3] Univ Glasgow, Sch Engn, Glasgow G12 8QQ, Lanark, Scotland
[4] Inst Max Von Laue Paul Langevin, F-38042 Grenoble 9, France
[5] Tan Delta Microwaves Ltd, Heriot EH38 5YF, Scotland
关键词
HIGH-TEMPERATURE SYNTHESIS; IN-SITU; ASSISTED SYNTHESIS; SCALE-UP; COMBUSTION SYNTHESIS; CATHODE MATERIAL; SINGLE-MODE; SILICON CARBONITRIDE; CATALYTIC-PROPERTIES; NEUTRON-DIFFRACTION;
D O I
10.1021/cr4002353
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The significant advances in the area of solid-state microwave (MW) synthesis are studied. MWs are broadly regarded as those electromagnetic waves which are situated between infrared and radio wavelengths in the electromagnetic spectrum, with wavelengths between 0.01 and 1 m, corresponding to frequencies between 0.3 and 300 GHz. MW radiation interacts directly with the reaction components, so the sample alone is heated with minimal need for energy to be expended in heating furnaces, containment materials, and the sample environment. While absorption of MWs in solid and liquid samples is frequency dependent, it is, in effect, nonquantized. Instead, the material behaves as though reacting to a high-frequency electric field. Manipulating MW penetration depth will be vital to develop the flow processes that underpin manufacturing and mass production.
引用
收藏
页码:1170 / 1206
页数:37
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