Carbon Capture and Sustainable Utilization by Algal Polyacrylonitrile Fiber Production: Process Design, Techno-Economic Analysis, and Climate Related Aspects

被引:22
作者
Arnold, Uwe [1 ]
Brueck, Thomas [2 ,3 ]
De Palmenaer, Andreas [4 ]
Kuse, Kolja [5 ]
机构
[1] AHP GmbH & Co KG, Karl Heinrich Ulrichs Str 11, D-10787 Berlin, Germany
[2] Tech Univ Munich, Dept Chem, Synthet Biotechnol, Lichtenberg Str 4, D-85748 Garching, Germany
[3] Tech Univ Munich, Dept Chem, TUM AlgaeTec Ctr, Lichtenberg Str 4, D-85748 Garching, Germany
[4] Rhein Westfal TH Aachen, Inst Text Technol, Otto Blumenthal Str 1, D-52074 Aachen, Germany
[5] TechnoCarbonTechnol GbR, Oberfohringer Str 175 A, D-81925 Munich, Germany
关键词
BIODIESEL; MICROALGAE; METHANOL; CONVERSION;
D O I
10.1021/acs.iecr.7b04828
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Carbon capture and sustainable utilization (CCU) is essential to accomplishing the targets of 2015's Paris Agreement. A promising option consists of algal based CO, conversion into lipid rich biomass with further processing into polyacrylonitrile (PAN) fiber, the major precursor for carbon fiber production. A first feasibility analysis was carried out under multiple constraints for price, byproduct yield, and consumption of land, CO2, and energy. Several process -route alternatives were composed, modeled, and compared in terms of mass and energy flows, resource needs, and cost. To quantify risks from market and modeling uncertainties, we conducted a primary techno-economic analysis (TEA) with variable process pathways in a dynamic economic model of a related project company (SPV), embedded in a Monte Carlo simulation. First results indicate that process combinations with algal biodiesel-production and biomass-liquefaction (BtL) components come close to meeting the multiple constraints and justify progressing to extended research and development activities.
引用
收藏
页码:7922 / 7933
页数:12
相关论文
共 55 条
[1]  
American Chemical Society National Historic Chemical Landmarks, SOH ACR PROC
[2]  
[Anonymous], 2016, NAT ALG BIOF REV
[3]  
[Anonymous], 2012, ANLESD124 PAC NW NAT
[4]   Open thin-layer cascade reactors for saline microalgae production evaluated in a physically simulated Mediterranean summer climate [J].
Apel, A. C. ;
Pfaffinger, C. E. ;
Basedahl, N. ;
Mittwollen, N. ;
Goebel, J. ;
Sauter, J. ;
Brueck, T. ;
Weuster-Botz, D. .
ALGAL RESEARCH-BIOMASS BIOFUELS AND BIOPRODUCTS, 2017, 25 :381-390
[5]  
Arnold U., 2018, IND ENG CHEM RES, DOI [10.1021/acsiecr.7b04841, DOI 10.1021/ACSIECR.7B04841]
[6]   Economic risk analysis of decentralized renewable energy infrastructures - A Monte Carlo Simulation approach [J].
Arnold, Uwe ;
Yildiz, Oezguer .
RENEWABLE ENERGY, 2015, 77 :227-239
[7]   The carbon footprint and non-renewable energy demand of algae-derived biodiesel [J].
Azadi, Pooya ;
Brownbridge, George ;
Mosbach, Sebastian ;
Smallbone, Andrew ;
Bhave, Amit ;
Inderwildi, Oliver ;
Kraft, Markus .
APPLIED ENERGY, 2014, 113 :1632-1644
[8]  
Bandi A., 2004, GEWINNUNG METHANOL B
[9]   The future viability of algae-derived biodiesel under economic and technical uncertainties [J].
Brownbridge, George ;
Azadi, Pooya ;
Smallbone, Andrew ;
Bhave, Amit ;
Taylor, Benjamin ;
Kraft, Markus .
BIORESOURCE TECHNOLOGY, 2014, 151 :166-173
[10]   Life Cycle Assessment comparison of two ways for acrylonitrile production: the SOHIO process and an alternative route using propane [J].
Cespi, Daniele ;
Passarini, Fabrizio ;
Neri, Esmeralda ;
Vassura, Ivano ;
Ciacci, Luca ;
Cavani, Fabrizio .
JOURNAL OF CLEANER PRODUCTION, 2014, 69 :17-25