Molecular recognition of carbohydrates through directional hydrogen bonds by urea-appended porphyrins in organic media

被引:2
|
作者
Kim, YH [1 ]
Hong, JI [1 ]
机构
[1] Seoul Natl Univ, Coll Nat Sci, Sch Chem, Seoul 151747, South Korea
关键词
D O I
10.1002/1521-3773(20020816)41:16<2947::AID-ANIE2947>3.0.CO;2-H
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sugar receptors: Urea-appended porphyrins were the most effective binding agent for pyranosides in chloroform and still very effective even in the presence of hydroxylic cosolvents. The combination of a rigid porphyrin skeleton and acyclic, flexible, yet preorganized polar urea groups aligned in a rigid platform (see picture) enabled three-dimensional recognition of carbohydrates.
引用
收藏
页码:2947 / 2950
页数:4
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