共 3 条
Molecular recognition of carbohydrates through directional hydrogen bonds by urea-appended porphyrins in organic media
被引:2
|作者:
Kim, YH
[1
]
Hong, JI
[1
]
机构:
[1] Seoul Natl Univ, Coll Nat Sci, Sch Chem, Seoul 151747, South Korea
关键词:
D O I:
10.1002/1521-3773(20020816)41:16<2947::AID-ANIE2947>3.0.CO;2-H
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Sugar receptors: Urea-appended porphyrins were the most effective binding agent for pyranosides in chloroform and still very effective even in the presence of hydroxylic cosolvents. The combination of a rigid porphyrin skeleton and acyclic, flexible, yet preorganized polar urea groups aligned in a rigid platform (see picture) enabled three-dimensional recognition of carbohydrates.
引用
收藏
页码:2947 / 2950
页数:4
相关论文