Rotational spectrum of the AsH2 radical in its ground state, studied by far-infrared laser magnetic resonance

被引：13

作者：

Hughes, RA

Brown, JM

Evenson, KM

机构：

[1] Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

[2] Natl Inst Stand & Technol, Boulder, CO 80303 USA

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2000年 / 200卷 / 02期

基金：

美国国家航空航天局;

关键词：

D O I：

10.1006/jmsp.1999.8037

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The rotational spectrum of AsH2 in its ground (X) over tilde(2)B(1) electronic state has been recorded using a far-infrared laser magnetic resonance spectrometer. The AsH2 radical was produced inside the spectrometer cavity by the reaction of arsine (AsH3) with fluorine atoms. Hyperfine splittings from both As-75 and H-1 nuclei were observed, and analysis of the spectra has yielded accurate values for rotational, hyperfine, and Zeeman parameters. (C) 2000 Academic Press.

引用

页码：210 / 228

页数：19

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