Identifying phase transition behavior in Bi1/2Na1/2TiO3-BaTiO3 single crystals by piezoresponse force microscopy

被引:29
作者
Lee, Hyun-Young [1 ]
Wang, Ke [1 ]
Yao, Fang-Zhou [1 ]
Sun, Wei [1 ]
Zhou, Zhen [1 ]
Zhang, Mao-Hua [1 ]
Li, Xiaobing [2 ]
Luo, Haosu [2 ]
Lee, Jae-Shin [3 ]
Li, Jing-Feng [1 ]
机构
[1] Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Funct Mat & Devices, 215 Chengbei Rd, Shanghai 201800, Peoples R China
[3] Univ Ulsan, Sch Mat Sci & Engn, Ulsan 44610, South Korea
关键词
FREE PIEZOELECTRIC CERAMICS; ELECTRICAL-PROPERTIES; FERROELECTRIC MATERIALS; RELAXOR FERROELECTRICS; RAMAN-SPECTROSCOPY; THIN-FILMS; SYSTEM; POLARIZATION;
D O I
10.1063/1.4982910
中图分类号
O59 [应用物理学];
学科分类号
摘要
Using piezoresponse force microscopy (PFM) and Raman spectroscopy, we studied the local temperature-dependent piezoelectric properties and phase structures of 0.95(Bi0.5Na0.5)TiO(3-)0.05BaTiO(3) (BNT-BT) single crystals. Local-area PFM revealed non-ergodic relaxor behavior around 160 degrees C. Switching spectroscopy-PFM (SS-PFM) results also supported the transition around 160 degrees C, with a gradual decrease in hysteresis width and nucleation bias. Moreover, Raman spectroscopy provided structural evidence of a phase transition in the same temperature region. These results are consistent with other theories of phase transitions in BNT-BT-based materials and verify the existence of a phase transition from a non-ergodic relaxor to ergodic relaxor of BNT-5.0%BT near 160 degrees C. Published by AIP Publishing.
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页数:7
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