Influence of molecular organization of an azido alcohol solution on the urethane formation kinetics

被引：1

作者：

Karpov, S. V. ^{[1
]}

Lodygina, V. P. ^{[1
]}

Malkov, G. V. ^{[1
]}

Badamshina, E. R. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, 1 Prosp Akad Semenova, Chernogolovka 142432, Moscow Region, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2016年 / 65卷 / 10期

关键词：

diazidopropanol; 1,6-hexamethylene diisocyanate; isopropanol; urethane formation; molecular organization of solution; association of azido alcohol; kinetics; LIQUID-PHASE REACTIONS; ISOPHORONE DIISOCYANATE; POLYURETHANE; ISOCYANATE; CATALYSIS; REAGENTS; INHIBITION; GLYCOLS; TOLUENE; MEDIA;

D O I：

10.1007/s11172-016-1599-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The quantitative data on the influence of molecular organization of CH2Cl2 solutions of diazidopropanol and its non-azide analog (isopropanol) and the concentrations of the alcohols and catalyst (dibutyltin dilaurinate) on the kinetics of urethane formation via the reaction with 1,6-hexamethylene diisocyanate were obtained. The series of reactivity were composed for various associates of hydroxyl groups of these alcohols in solutions in the catalytic and non-catalytic reactions.

引用

页码：2415 / 2420

页数：6

共 33 条

[1] Polyurethane macromers - new building blocks for acrylic hybrid emulsions with outstanding performance [J].