A one-dimensional cobalt(II) coordination polymer based on 2,4′-oxydibenzoic acid: poly[[[diaquabis[2-(4-carboxyphenoxy)benzoato-κO1]cobalt(II)]-μ-4,4′-bipyridine-κ2N:N′]dihydrate]

被引：1

作者：

Tang, Long ^{[1
]}

Fu, Feng ^{[1
]}

Wang, Ji-Jiang ^{[1
]}

Liu, Qi-Rui ^{[1
]}

Zhao, Hang-Hang ^{[1
]}

机构：

[1] Yanan Univ, Dept Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Shaanxi, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2014年 / 70卷

关键词：

crystal structure; one-dimensional coordination polymer; 2,4 '-oxydibenzoic acid; cobalt(II) complex; magnetic properties; X-ray powder diffraction; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; SORPTION PROPERTIES; LIGANDS;

D O I：

10.1107/S2053229614012066

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of CoSO4 with 2,4-oxydibenzoic acid (H(2)oba) and 4,4 '-bipyridine (bipy) under hydrothermal condition yielded a new one-dimensional cobalt(II) coordination polymer, {[Co(C14H9O5)(2)(C10H8N2)(H2O)(2)]center dot 2H(2)O}(n), which was characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, magnetic properties and single-crystal X-ray diffraction. The Co-II ions are connected by bipy ligands into infinite one-dimensional chains. The Hoba(-) ligands extend out from the two sides of the one-dimensional chain. O-H center dot center dot center dot O hydrogen bonding extends these chains into a two-dimensional supramolecular architecture.

引用

页码：654 / +

页数：10

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