Comprehensive ab initio studies of nuclear magnetic resonance shielding and coupling constants in XH•••O hydrogen-bonded complexes of simple organic molecules

被引:55
|
作者
Pecul, M
Leszczynski, J
Sadlej, J
机构
[1] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland
[2] Jackson State Univ, Dept Chem, Computat Ctr Mol Struct & Interact, Jackson, MS 39217 USA
来源
JOURNAL OF CHEMICAL PHYSICS | 2000年 / 112卷 / 18期
关键词
D O I
10.1063/1.481394
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of hydrogen-bond formation on the scalar spin-spin coupling constants and NMR shielding constants in CH2O-H2O, C2H2-H2O, CH3OH-H2O, and (HCOOH)(2) complexes has been calculated using correlated MO (MCSCF and MP2) methods. The hydrogen-bond transmitted spin-spin coupling constants are also reported. The iso- and anisotropic H-1 shielding constants are found to be the most general parameters of the hydrogen bond. The changes in (1)J(XH) coupling in the proton donor also correlate with the XH ... Y hydrogen bond strength. A similar correlation is found in the intermolecular (1h)J(HY) and (2h)J(XY) couplings. These couplings are substantial and dominated by the Fermi-contact term in contrast to the longer-range hydrogen-bond transmitted couplings where the noncontact terms prevail. (C) 2000 American Institute of Physics. [S0021-9606(00)30618-3].
引用
收藏
页码:7930 / 7938
页数:9
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