Synthesis of hybrid dendrimer-star polymers by the RAFT process

被引：63
作者：
Darcos, V
Duréault, A
Taton, D
Gnanou, Y
Marchand, P
Caminade, AM
Majoral, JP
Destarac, M
Leising, F
机构：
[1] Univ Bordeaux 1, CNRS, ENSCPB, Lab Chim Polymeres Organ, F-33607 Pessac, France
[2] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France
[3] Rhodia, Ctr Rech Aubervilliers, F-93308 Aubervilliers, France
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 18期
关键词：
D O I：
10.1039/b407508k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A first generation phosphorus-containing dendrimer with twelve terminal benzyl dithiobenzoate functions was designed and subsequently used as a multifunctional agent to derive hybrid star copolymers consisting of a dendritic core surrounded by twelve polystyrene branches by reversible addition-fragmentation chain transfer ( RAFT).
引用
收藏
页码：2110 / 2111
页数：2
相关论文
共 11 条
[1]   Thiocarbonylthio compounds (S=C(Z)S-R) in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization). Effect of the activating group Z [J].
Chiefari, J ;
Mayadunne, RTA ;
Moad, CL ;
Moad, G ;
Rizzardo, E ;
Postma, A ;
Skidmore, MA ;
Thang, SH .
MACROMOLECULES, 2003, 36 (07) :2273-2283
[2]   Thiocarbonylthio compounds [S=C(Ph)S-R] in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization). Role of the free-radical leaving group (R) [J].
Chong, YK ;
Krstina, J ;
Le, TPT ;
Moad, G ;
Postma, A ;
Rizzardo, E ;
Thang, SH .
MACROMOLECULES, 2003, 36 (07) :2256-2272
[3]   Star poly(ethylene oxide)s from carbosilane dendrimers [J].
Comanita, B ;
Noren, B ;
Roovers, J .
MACROMOLECULES, 1999, 32 (04) :1069-1072
[4]   Synthesis of multifunctional dithioesters using tetraphosphorus decasulfide and their behavior as RAFT agents [J].
Duréault, A ;
Taton, D ;
Destarac, M ;
Leising, F ;
Gnanou, Y .
MACROMOLECULES, 2004, 37 (15) :5513-5519
[5]   Investigation of the initiation behavior of a dendritic 12-arm initiator in atom transfer radical polymerization [J].
Heise, A ;
Diamanti, S ;
Hedrick, JL ;
Frank, CW ;
Miller, RD .
MACROMOLECULES, 2001, 34 (11) :3798-3801
[6]   Hyperbranched polymers as scaffolds for multifunctional reversible addition-fragmentation chain-transfer agents:: A route to polystyrene-core-polyesters and polystyrene-block-poly(butyl acrylate)-core-polyesters [J].
Jesberger, M ;
Barner, L ;
Stenzel, MH ;
Malmström, E ;
Davis, TP ;
Barner-Kowollik, C .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (23) :3847-3861
[7]   Dendrimers containing heteroatoms (Si, P, B, Ge, or Bi) [J].
Majoral, JP ;
Caminade, AM .
CHEMICAL REVIEWS, 1999, 99 (03) :845-880
[8]   Thioacylation reactions for the surface functionalization of phosphorus-containing dendrimers [J].
Marchand, P ;
Griffe, L ;
Caminade, AM ;
Majoral, JP ;
Destarac, M ;
Leising, F .
ORGANIC LETTERS, 2004, 6 (08) :1309-1312
[9]  
Moad G, 2000, POLYM INT, V49, P993, DOI 10.1002/1097-0126(200009)49:9<993::AID-PI506>3.0.CO
[10]  
2-6
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