Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb3Mg3TeP2O14

被引：155
作者：
Yu, Hongwei [1 ]
Zhang, Weiguo [1 ]
Young, Joshua [2 ,3 ]
Rondinelli, James M. [2 ]
Halasyamani, P. Shiv [1 ]
机构：
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
[2] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
[3] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19102 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2016年 / 138卷 / 01期
基金：
美国国家科学基金会;
关键词：
NONLINEAR-OPTICAL CRYSTAL; LARGE SHG RESPONSE; ABSORPTION-EDGE; BUILDING-BLOCK; POLAR MATERIAL; BORATE; UV; TELLURITE; CSPBCO3F; SYSTEM;
D O I：
10.1021/jacs.5b11712
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new ultraviolet nonlinear optical (NLO) material, Pb3Mg3TeP2O14 (PMTP), has been synthesized and characterized. The chiral material exhibits a large second harmonic generation (SHG) response of 13.5 x KDP (600 x alpha-SiO2), and the shortest absorption edge (250 nm) of reported materials with a strong SHG response (>10 x KDP). PMTP has a three-dimensional crystal structure of corner-shared MgO4, PO4, and TeO6 polyhedra, which form a [TeMg3P2O14](infinity) framework. Electronic structure calculations revealed that the stereo-active lone pair on the Pb2+ cation is critical to producing the substantial NLO response and that the NLO activity is further enhanced by the presence of triply bidentate Te6+ cations found in Te-O-O-Pb rings.
引用
收藏
页码：88 / 91
页数：4
相关论文
共 53 条
[31]   Structure and properties of crystals in the potassium titanyl phosphate family: A review [J].
Sorokina, N. I. ;
Voronkova, V. I. .
CRYSTALLOGRAPHY REPORTS, 2007, 52 (01) :80-93
[32]   Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System [J].
Sun, Chuan-Fu ;
Hu, Chun-Li ;
Xu, Xiang ;
Yang, Bing-Ping ;
Mao, Jiang-Gao .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (14) :5561-5572
[33]   BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response [J].
Sun, Chuan-Fu ;
Hu, Chun-Li ;
Xu, Xiang ;
Ling, Ji-Bei ;
Hu, Ting ;
Kong, Fang ;
Long, Xi-Fa ;
Mao, Jiang-Gao .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (27) :9486-+
[34]   Growth and properties of a noncentrosymmetric polyphosphate CsLa(PO3)4 crystal with deep-ultraviolet transparency [J].
Sun, Tongqing ;
Shan, Pai ;
Chen, Hong ;
Liu, Xuanwen ;
Liu, Hongde ;
Chen, Shaolin ;
Cao, Ya'an ;
Kong, Yongfa ;
Xu, Jingjun .
CRYSTENGCOMM, 2014, 16 (45) :10497-10504
[35]   ABSORPTION EDGE AND INTERNAL ELECTRIC FIELDS IN AMORPHOUS SEMICONDUCTORS [J].
TAUC, J .
MATERIALS RESEARCH BULLETIN, 1970, 5 (08) :721-+
[36]   RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material [J].
Tran, T. Thao ;
He, Jiangang ;
Rondinelli, James M. ;
Halasyamani, P. Shiv .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (33) :10504-10507
[37]   Role of Acentric Displacements on the Crystal Structure and Second-Harmonic Generating Properties of RbPbCO3F and CsPbCO3F [J].
Tran, T. Thao ;
Halasyamani, P. Shiv ;
Rondinelli, James M. .
INORGANIC CHEMISTRY, 2014, 53 (12) :6241-6251
[38]   Na2CsBe6B5O15: An Alkaline Beryllium Borate as a Deep-UV Nonlinear Optical Crystal [J].
Wang, Shichao ;
Ye, Ning .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (30) :11458-11461
[39]   Designing a Deep-Ultraviolet Nonlinear Optical Material with a Large Second Harmonic Generation Response [J].
Wu, Hongping ;
Yu, Hongwei ;
Yang, Zhihua ;
Hou, Xueling ;
Su, Xin ;
Pan, Shilie ;
Poeppelmeier, Kenneth R. ;
Rondinelli, James M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (11) :4215-4218
[40]   K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge [J].
Wu, Hongping ;
Pan, Shilie ;
Poeppelmeier, Kenneth R. ;
Li, Hongyi ;
Jia, Dianzeng ;
Chen, Zhaohui ;
Fan, Xiaoyun ;
Yang, Yun ;
Rondinelli, James M. ;
Luo, Haosu .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (20) :7786-7790
123456