High-energy-density materials:: Synthesis and characterization of N5+[P(N3)6]-, N5+[B(N3)4]-, N5+[HF2]-•nHF,N5+[BF4]-, N5+[PF6]-, and N5+[SO3F]-

被引：130

作者：

Haiges, R ^{[1
]}

Schneider, S ^{[1
]}

Schroer, T ^{[1
]}

Christe, KO ^{[1
]}

机构：

[1] Univ So Calif, Loker Hydrocarbon Res Inst, Los Angeles, CA 90089 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 37期

关键词：

azides; high energy-density materials (HEDM); nitrogen; polynitrogen chemistry; vibrational spectroscopy;

D O I：

10.1002/anie.200454242

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

23 nitrogens and only one phosphorus: The N5+ ion is combined with energetic anions in the form of N5+[P(N 3)6]- and N5+[B(N 3)4]- (see scheme), containing 91 and 96 wt%, respectively, of nitrogen. Also, the thermally unstable compound N 5HF2·n HF is prepared by metathesis from N 5SbF6 and CsHF2. Its usefulness as a reagent for the synthesis of new N5+ salts is demonstrated with the preparation of N5PF6, N5BF4, and N5SO3F.

引用

页码：4919 / 4924

页数：6

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