Copper-decorated covalent organic framework as a heterogeneous photocatalyst for phosphorylation of terminal alkynes

被引：87

作者：

Chen, Yu-Xuan ^{[1
]}

Zhang, Mo ^{[1
]}

Zhang, Shuai-Zheng ^{[1
]}

Hao, Zhi-Qiang ^{[1
]}

Zhang, Zhan-Hui ^{[1
]}

机构：

[1] Hebei Normal Univ, Coll Chem & Mat Sci, Natl Expt Chem Teaching Ctr, Hebei Key Lab Organ Funct Mol, Shijiazhuang 050024, Hebei, Peoples R China

来源：

GREEN CHEMISTRY | 2022年 / 24卷 / 10期

基金：

中国国家自然科学基金;

关键词：

ONE-POT SYNTHESIS; P BOND FORMATION; H-PHOSPHONATES; 1-ALKYNYLPHOSPHINE SULFIDES; ALKYNYLPHOSPHINE OXIDES; COUPLING REACTION; HIGHLY EFFICIENT; CATALYST; PHOTOREDOX; TRANSFORMATIONS;

D O I：

10.1039/d2gc00754a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A layered covalent organic framework (COF) material based on an imine-linkage with high thermal and chemical stability was prepared using a deep eutectic solvent (DES) as the green medium. The as-synthesized COF materials were modified with catalytic copper. This crystalline and highly porous catalyst shows excellent photocatalytic performance in visible-light-driven coupling reactions of terminal alkynes with H-phosphonates at room temperature. In addition, the photocatalyst could be recovered and recycled eight times without significant loss of its reactivity.

引用

页码：4071 / 4081

页数：11

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